863983-68-0

Basic information

• Product Name: methyl (1S,3R,4S,5S,6S)-6-chloro-1,3,4,5-tetrahydroxycyclohexanecarboxylate
• CAS NO: 863983-68-0
• Molecular Weight: 240.641
• Mol File: 863983-68-0.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: methyl (1S,3R,4S,5S,6S)-6-chloro-1,3,4,5-tetrahydroxycyclohexanecarboxylate(CAS DataBase Reference)
• NIST Chemistry Reference: methyl (1S,3R,4S,5S,6S)-6-chloro-1,3,4,5-tetrahydroxycyclohexanecarboxylate(863983-68-0)
• EPA Substance Registry System: methyl (1S,3R,4S,5S,6S)-6-chloro-1,3,4,5-tetrahydroxycyclohexanecarboxylate(863983-68-0)

Safety Data

• Hazardous Substances Data: 863983-68-0(Hazardous Substances Data)

Upstream product

• 863983-56-6 (1S,3R,4R,5S,6S)-4-(tert-butyldimethylsiloxy)-6-chloro-1,5-dihydroxycyclohexane-1,3-carbolactone 
• 67-56-1 methanol 
• 189366-37-8 (1R,3R,4S)-4-(tert-butyldimethylsiloxy)-1-hydroxy-5-oxocyclohexane-1,3-carbolactone 
• 77-95-2 D-(-)-quinic acid 
• 863983-55-5 (1S,3R,4S,6R)-4-(tert-butyldimethylsiloxy)-6-chloro-1-hydroxy-5-oxocyclohexane-1,3-carbolactone 
• 868526-03-8 (1R,4S,5R)-1,4-Dihydroxy-6-oxa-bicyclo[3.2.1]octane-3,7-dione 

Relevant articles and documents

Synthetic study toward antitumour natural product pericosine A

The stereoselective total synthesis of methyl (3R,4S,5S,6R)-6-chloro-3,4,5- trihydroxy-1-cyclohex-1-enecarboxylate (1), which had been reported as the antitumour marine natural product pericosine A, from (-)-quinic acid was achieved. From the total synthesis, it was confirmed that the reported stereostructure of pericosine A was incorrect because the spectroscopic data of the synthetic product were not identical with those of the natural compound. Copyright