866249-74-3Relevant articles and documents
Synthesis of a new type of glycosidic linkage: Acetal-linked disaccharides and trisaccharides of acyclic and cyclic sugars
Madhusudan, Soni Kamlesh,Misra, Anup Kumar
, p. 3196 - 3205 (2007/10/03)
New types of di- and trisaccharides related to a unique trisaccharide present in the cell walls of Proteus have been synthesized by coupling of acyclic sugar dithioacetals and di- and monohydroxy cyclic sugars. In this class of compounds an acyclic sugar is linked to a cyclic sugar through an acetal linkage. The formation of these acetal-linked pseudodi- and -trisaccharides has been achieved by a generalized reaction procedure mediated by 1,3-dibromo-5,5-dimethylhydantoin under mild, metal-free and neutral conditions. Sixteen protected and twelve deprotected di- and trisaccharides related to the trisaccharide found in the Proteus cell wall have been synthesized. Wiley-VCH Verlag GmbH & Co. KGaA, 2005.