87258-30-8

Basic information

• Product Name: 6-oxo-6-phenylhexanal
• Synonyms: 6-oxo-6-phenylhexanal
• CAS NO: 87258-30-8
• Molecular Weight: 190.242
• Mol File: 87258-30-8.mol
• Article Data: 39

Chemical Properties

• CAS DataBase Reference: 6-oxo-6-phenylhexanal(CAS DataBase Reference)
• NIST Chemistry Reference: 6-oxo-6-phenylhexanal(87258-30-8)
• EPA Substance Registry System: 6-oxo-6-phenylhexanal(87258-30-8)

Safety Data

• Hazardous Substances Data: 87258-30-8(Hazardous Substances Data)

Upstream product

• 5775-23-5 1-phenylcyclohexene oxide 
• 771-98-2 1-Phenylcyclohexene 
• 17851-49-9 5-hydroxypentyl phenyl ketone 
• 15447-62-8 1-phenyl-hex-5-yn-1-one 
• 176853-30-8 6,6-dimethoxy-6-phenylhexanal dimethyl acetal 
• 27167-34-6 trans-1-Phenylcyclohexane-1,2-diol 
• 186581-53-3 diazomethane 
• 4066-82-4 1-phenyl-hexane-1,6-diol 
• 4144-62-1 5-benzoylvaleric acid 
• 1589-60-2 1-phenylcyclohexanol 
• 108-94-1 cyclohexanone 
• 100-58-3 phenylmagnesium bromide 
• 827-52-1 1-phenyl-1-cyclohexane 
• 20614-61-3 cyclohexyl-1-phenyl-1-hydroperoxide 

Downstream Products

• 15177-05-6 1-phenylhept-6-en-1-one 
• 32346-66-0 (±)-2-hydroxycyclopentyl(phenyl)methanone 
• 32346-66-0 (2-hydroxy-cyclopentyl)-phenyl-methanone 
• 1174579-69-1 C₁₆H₂₃NO₂S 
• 1026732-62-6 ethyl (E)-8-oxo-8-phenyloct-2-enoate 
• 771-98-2 1-Phenylcyclohexene 
• 17851-49-9 5-hydroxypentyl phenyl ketone 
• 121029-77-4 6-hydroxy-6-phenyl-hexanal 
• 1359939-36-8 6-acetoxy-6-phenylhexanal 
• 15447-62-8 1-phenyl-hex-5-yn-1-one 
• 1313885-32-3 6-cyclopentenyl-1-phenylhex-5-yn-1-one 
• 1226854-90-5 5-[5-(5-oxo-5-phenylpentyl)-3-vinyl-tetrahydro-furan-2-yl]-1-phenylpentan-1-one 
• 1222087-99-1 (8E)-1,9-diphenylnona-6,8-dien-1-one 
• 1671-75-6 Heptanophenone 

Relevant articles and documents

A copper(II)-mediated regioselective cyclization-acetoxylation of 6,8-Dien-1-ones for the synthesis of functionalized cyclopentanes

This paper describes a copper(II) acetate-mediated cyclization- acetoxylation of 6,8-dien-1-ones in the presence of sodium acetate as base. A variety of functionalized cyclopentanes containing synthetic useful allylic alcohol moieties with three contiguou

Iron-catalyzed chemoselective hydride transfer reactions

A Diaminocyclopentadienone iron tricarbonyl complex has been applied in chemoselective hydrogen transfer reductions. This bifunctional iron complex demonstrated a broad applicability in mild conditions in various reactions, such as reduction of aldehydes over ketones, reductive alkylation of various functionalized amines with functionalized aldehydes and reduction of α,β-unsaturated ketones into the corresponding saturated ketones. A broad range of functionalized substrates has been isolated in excellent yields with this practical procedure.

Visible-light-promoted site-specific and diverse functionalization of a c(sp3)-c(sp3) bond adjacent to an arene

We report here a strategy for inert C-C bond functionalization. Site-specific cleavage and functionalization of a saturated C(sp3)-C(sp3) bond via a visible-light-induced radical process have been achieved. The general features of this reaction are as follows. (1) Both linear and cyclic C(sp3)-C(sp3) bonds with a vicinal arene can be specifically functionalized. (2) One carbon is converted into a ketone, and another can be tunably converted into nitrile, peroxide, or halide. (3) The typical conditions include 1.0 mol % of Ru(bpy)3Cl2, 1.0 or 5.0 equiv of Zhdankin reagent, white CFL (24 W), open flask, and room temperature. These reactions offer powerful tools to modify carbon skeletons that are intractable by conventional methods. Good selectivity and functional group tolerance, together with mild and open air conditions, make these transformations valuable and attractive.