90923-99-2Relevant articles and documents
Propargyl anthranilate derivatives and their application in the synthesis of rings containing 1,2,3-triazolo motifs
Hradilova, Ludmila,Grepl, Martin,Hlavac, Jan,Lycka, Antonin,Hradil, Pavel
, p. 528 - 533 (2013)
Propargyl anthranilate, a simple and less studied molecule with several reactive sites, is widely applicable in organic synthesis. An optimized synthesis of this compound and its derivatives and the preparation of azide derivatives are described. The optimized process of the known intramolecular cyclization is described, and the unknown intermolecular cyclizations of these azido derivatives and formation of a macrocycle are discussed.
SYNTHESIS OF -TRIAZOLOBENZOXAZEPINES via INTRAMOLECULAR AZIDE CYCLOADDITION
Garanti, Luisa,Molteni, Giorgio,Zecchi, Gaetano
, p. 291 - 296 (2007/10/02)
Starting from isatoic anhydride and propargyl alcohols, we developed a synthetic approach to the title compounds, were the key step is an intramolecular cycloaddition of the azido group onto the acetylenic bond.