91667-55-9

Basic information

• Product Name: 1,2:3,6:4,5-tri-O-isopropylidene-D-mannitol
• Synonyms: 1,2:3,6:4,5-tri-O-isopropylidene-D-mannitol
• CAS NO: 91667-55-9
• Molecular Weight: 302.368
• Mol File: 91667-55-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 1,2:3,6:4,5-tri-O-isopropylidene-D-mannitol(CAS DataBase Reference)
• NIST Chemistry Reference: 1,2:3,6:4,5-tri-O-isopropylidene-D-mannitol(91667-55-9)
• EPA Substance Registry System: 1,2:3,6:4,5-tri-O-isopropylidene-D-mannitol(91667-55-9)

Safety Data

• Hazardous Substances Data: 91667-55-9(Hazardous Substances Data)

Upstream product

• 69-65-8 mannitol 
• 116-11-0 2-Methoxypropene 
• 77-76-9 2,2-dimethoxy-propane 
• 67-64-1 acetone 

Downstream Products

• 3969-61-7 2,3,5,6-di-isopropyIidene-1,4-dihydroxy-D-mannitol 
• 38145-92-5 4,5-mono-O-isopropylidene-D-mannitol 
• 4306-35-8 1,2-mono-O-isopropylidene-D-mannitol 
• 1707-77-3 1,2:5,6-di-O-isopropylidene-D-mannitol 

Relevant articles and documents

THE SYNTHESIS OF 1,2:5,6-DI-O-ISOPROPYLIDENE-D-MANNITOL: A COMPARATIVE STUDY

Three different methods of acetonation of D-mannitol using (a) acetone and zinc chloride, (b) 2,2-dimethoxypropane, 1,2-dimethoxyethane, and tin(II)chloride, and (c) 2-methoxypropane, N,N-dimethylformamide, and p-toluenesulfonic acid were studied in detail and compared, using gas-liquid chromatographic techniques.In each reaction, isomeric diacetals are formed, but method a gives the 1,2:5,6-diacetal in the highest yield (63percent).Methods b and c give a more complex mixture of acetals than proposed in the literature, and both methods are less economical than a.A new 1,2:3,6:4,5-tri-O-isopropylidene-D-mannitol could be separated, and its graded hydrolysis was compared to that of the 1,2:3,4:5,6-triacetal.