934832-26-5Relevant articles and documents
Highly stereoselective synthesis of homoallylic amines based on addition of allyltrichlorosilanes to benzoylhydrazones
Hirabayashi,Ogawa,Sugiura,Kobayashi
, p. 9493 - 9499 (2001)
Allyltrichlorosilanes reacted with benzoylhydrazones in DMF without the use of any catalyst to afford the corresponding homoallylic benzoylhydrazines in good to high yields. The reactions proceeded at 0°C to room temperature under mild conditions. In addi
Preparation method of allyl amine
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Paragraph 0006; 0008, (2016/11/24)
The invention provides a preparation method of allyl amine.Under the conditions of being at the room temperature and the normal pressure and being free of inert gas shielding, allylation of acylhydrazone catalyzed by a sulfamide-loaded dendritic macromolecule catalyst is conducted, the reaction time is about two hours, and a quite good yield can be obtained; the loaded catalyst can be recycled through methanol recrystallization, and a quite good effect is achieved after the catalytic reaction is continued; environmentally friendliness and economic benefits are achieved to a certain extent.
A mild and efficient three-component synthesis of secondary and tertiary homoallylic hydrazides
Lee, Bum Seok,Jang, Doo Ok
, p. 3123 - 3130 (2013/06/26)
A three-component reaction that involved a carbonyl compound, benzoylhydrazine, allyl bromide, and indium in the presence of readily available Zn(ClO4)2·6H2O was developed for the syntheses of secondary and tertiary homoal
