93714-50-2

Basic information

• Product Name: Spiro[2.3]hexane, 1-phenyl-
• CAS NO: 93714-50-2
• Molecular Formula: C12H14
• Molecular Weight: 158.243
• Mol File: 93714-50-2.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: Spiro[2.3]hexane, 1-phenyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Spiro[2.3]hexane, 1-phenyl-(93714-50-2)
• EPA Substance Registry System: Spiro[2.3]hexane, 1-phenyl-(93714-50-2)

Safety Data

• Hazardous Substances Data: 93714-50-2(Hazardous Substances Data)

Upstream product

• 100-42-5 styrene 
• 33742-81-3 1,1-dibromocyclobutane 
• 75-11-6 diiodomethane 
• 5244-75-7 benzylidenecyclobutane 
• 93685-08-6 7-Phenyl-5,6-diaza-spiro[3.4]oct-5-ene 
• 73013-83-9 1-benzyl-1-hydroxycyclobutane 
• 29817-09-2 1-methylene-2-phenylcyclopropane 
• 97-93-8 triethylaluminum 
• 107-05-1 3-chloroprop-1-ene 

Relevant articles and documents

Synthesis and transformations of metallacycles 37. Cp2ZrCl 2-Catalyzed cycloalumination of substituted methylidenecyclopropane with Et3Al

Cycloalumination of substituted methylidenecyclopropanes with Et 3Al catalyzed by Cp2ZrCl2 affords alumaspiro[2.4]heptanes in 64-92% yields.

Synthesis, Structure, and Reactions of Stable Titanacyclopentanes

Titanacyclic compounds of the formula Cp*2Ti(CH2CH2C(CH2CHR)CH2) (5a; R=H and 5b; R=C6H5, Cp*=pentamethylcyclopentadienyl), the first stable titanacyclopentanes, have been prepared by the reaction of bis(pentamethylcyclopentadienyl)titanium-ethylene complex (3) with methylenecyclopropanes (4), and their structures were determined based on both spectroscopic data and X-ray crystallography.Complex 5b crystallized in space group P21/a (Z=4) with cell constants, a=21.832(3), b=8.580(1), c=14.759(2) Angstroem, β=96.81(1) deg, U=2744.9(6) Angstroem3 (4261 reflections, R=0.053).The reaction of 5 with carbon monoxide afforded spiroheptan-5-ones in 98percent yield.The thermal decomposition of 5 has been investigated, and possible mechanisms of the reactions have been proposed based on deuterium-labeled experiments.A novel formal reductive elimination of organic ligands giving 1-phenylspirohexane has been observed in the thermolysis of 5b.A structure-reactivity relationship has been discussed.