955084-10-3

Basic information

• Product Name: 5,5-difluoro-10-(p-tolyl)-5H-dipyrrolo[1,2-c:2',1'-f][1,3,2]diazaborinin-4-ium-5-uide
• Synonyms: 5,5-difluoro-10-(p-tolyl)-5H-dipyrrolo[1,2-c:2',1'-f][1,3,2]diazaborinin-4-ium-5-uide
• CAS NO: 955084-10-3
• Molecular Weight: 282.1
• Mol File: 955084-10-3.mol
• Article Data: 7

Chemical Properties

• CAS DataBase Reference: 5,5-difluoro-10-(p-tolyl)-5H-dipyrrolo[1,2-c:2',1'-f][1,3,2]diazaborinin-4-ium-5-uide(CAS DataBase Reference)
• NIST Chemistry Reference: 5,5-difluoro-10-(p-tolyl)-5H-dipyrrolo[1,2-c:2',1'-f][1,3,2]diazaborinin-4-ium-5-uide(955084-10-3)
• EPA Substance Registry System: 5,5-difluoro-10-(p-tolyl)-5H-dipyrrolo[1,2-c:2',1'-f][1,3,2]diazaborinin-4-ium-5-uide(955084-10-3)

Safety Data

• Hazardous Substances Data: 955084-10-3(Hazardous Substances Data)

Upstream product

• 104-87-0 4-methyl-benzaldehyde 
• 147804-55-5 5-(4-methylphenyl)dipyrromethane 
• 1606994-41-5 5-(4-methylphenyl)dipyrrin 
• 5720-05-8 4-methylphenylboronic acid 
• 31614-66-1 tributyl(p-tolyl)stannane 
• 109-63-7 boron trifluoride diethyl etherate 
• 109-97-7 pyrrole 

Downstream Products

• 1588866-87-8 C₃₀H₂₈BBrF₂N₂S₂ 
• 1588866-88-9 C₃₀H₂₇BBrF₂IN₂S₂ 
• 1588866-96-9 C₄₄H₄₃BBr₂F₂N₂S₄ 
• 1354013-66-3 4,4-difluoro-2,6-diiodo-8-(4-tolyl)-4-bora-3a,4a-diaza-s-indacene 
• 1588866-84-5 2,6-dibromo-4,4-difluoro-8-(4-methylphenyl)-4-bora-3a,4a-diaza-s-indacene 
• 1588866-85-6 C₃₀H₂₉BF₂N₂S₂ 
• 1588866-86-7 C₄₄H₄₅BF₂N₂S₄ 
• 1234098-78-2 3-(phenacyl)-8-(p-tolyl)-4,4-difluoro-4-bora-3a,4a-diaza-s-indacene 
• 1234098-80-6 ethyl (8-phenyl-4,4-difluoro-4-bora-3a,4a-diaza-s-indacen-3-yl) phenylacetate 
• 1354013-80-1 4,4-difluoro-2,3,5,6-tetraiodo-8-(4-methylphenyl)-4-bora-3a,4a-diaza-s-indacene 

Relevant articles and documents

BODIPY based A-D-A molecules: Effect of CF3 group substitution at meso phenyl group

Two pairs of A-D-A molecules have been synthesized with fluorene and benzodithiophene as the central donor subunits and terminal BODIPY units, functionalized with either a 4-methylphenyl or 4-trifluoromethylphenyl group at the meso position. The effect of the para substituent of the meso phenyl group on the photophysical properties of these molecules is studied through steady state absorption and fluorescence spectroscopy as well as femtosecond transient absorption and time resolved fluorescence spectroscopy techniques. Applicability of these molecules as donors in solution processed solar cell active layers was investigated through time resolved microwave conductivity measurements on blends with PC60BM acceptor, which shows a varying yield of charge transfer with choice of substituent. Transient absorption spectroscopy is then employed to investigate the role of the 4-trifluoromethylphenyl group in altering the efficiency of charge transfer from these A-D-A molecules to PC60BM. The results show a consistent picture of picosecond charge transfer and a component of a few hundred ps geminate recombination that results in a small yield of long-lived free charges optimized for the methylphenyl derivatives.

Taurine substituted bodipy fluorescent compound and preparation method and application thereof

The invention provides a taurine substituted bodipy fluorescent compound, and further provides a preparation method of the taurine substituted bodipy fluorescent compound. The method comprises the following steps: reacting 8-(4-position substituted phenyl)-3, 5-diiodo-1, 2, 6, 7-tetra-substituted bodipy and 1,2-disubstituted taurine under the conditions of an additive, a catalyst and a solvent toobtain 8-(4-position substituted phenyl) 3-iodo-5-(2-ethanesulfonic acid) amine)-1,2,6,7-tetra-substituted bodipy and 8-(4-position substituted phenyl) 3,5-bis((2-ethanesulfonic acid) amine)-1,2,6,7-tetra-substituted bodipy. According to the taurine substituted bodipy fluorescent compound, by a cheap metal catalyzed direct C-X/N-H activating method, taurine with biological activity is introducedat a 3,5 activated site of star fluorescent molecule bodipy, and therefore, a novel fluorescent molecule framework is formed.

Indole-BODIPY: A turn-on chemosensor for Hg2+ with application in live cell imaging

A new BODIPY, 2-(bis(1-methyl-1H-indol-3-yl)methyl)-4,4-difluoro-4-bora-3a,4a-diaza-s-indacene bearing bis(1-methyl-1H-indol-3-yl)methyl unit at the β-pyrrolic position acting as a 'turn-on' chemosensor for Hg2+ in solution as well as in HeLa cells, is synthesized. The 'off' state of the probe is proposed to be a result of a photoinduced electron transfer (PET) process which gets inhibited in the presence of Hg2+ ions, leading to the 'on' state. We propose that the detection of Hg2+ ions proceeds via the interaction of the π-electron density of the electron rich indolic units of the BODIPY group with that of the acidic Hg2+ ions, restricting the PET. The sensing protocols are established by various spectroscopic/electrochemical/DFT studies.