97483-86-8

Basic information

• Product Name: 3-methoxyphenyl 2,2-dimethylpropionate
• Synonyms: 3-methoxyphenyl 2,2-dimethylpropionate
• CAS NO: 97483-86-8
• Molecular Weight: 208.257
• Mol File: 97483-86-8.mol
• Article Data: 6

Chemical Properties

• CAS DataBase Reference: 3-methoxyphenyl 2,2-dimethylpropionate(CAS DataBase Reference)
• NIST Chemistry Reference: 3-methoxyphenyl 2,2-dimethylpropionate(97483-86-8)
• EPA Substance Registry System: 3-methoxyphenyl 2,2-dimethylpropionate(97483-86-8)

Safety Data

• Hazardous Substances Data: 97483-86-8(Hazardous Substances Data)

Upstream product

• 150-19-6 O-methylresorcine 
• 3282-30-2 pivaloyl chloride 
• 1538-75-6 2,2-dimethylpropanoic anhydride 
• 766-85-8 3-methoxy-1-iodobenzene 
• 75-98-9 Trimethylacetic acid 
• 33285-71-1 1-methoxy-3-trimethylsilyloxybenzene 
• 37170-49-3 trimethylsilyl 2,2-dimethylpropionate 

Downstream Products

• 883988-36-1 4-hydroxy-2-methoxyphenylacetic acid 
• 1292299-16-1 4-(2-bromoacetyl)-3-methoxyphenyl pivalate 
• 1292299-17-2 4-(2-(diethoxyphosphoryloxy)acetyl)-3-methoxyphenyl pivalate 
• 1292298-92-0 diethyl (2-(4-hydroxy-2-methoxyphenyl)-2-oxoethyl)phosphate 
• 1292299-15-0 4-(2-chloroacetyl)-3-methoxyphenyl pivalate 
• 1048371-87-4 (3-methoxyphenyl)triethylsilane 
• 1527-89-5 3-methoxybenzonitrile 
• 404377-69-1 2-(3-methoxyphenyl)-5-methyl-1,3-benzoxazole 

Relevant articles and documents

Palladium-Catalyzed Esterification of Carboxylic Acids with Aryl Iodides

The first palladium-catalyzed esterification of carboxylic acids with aryl iodides is described. A palladium-based catalytic system consisting of IBnF (1,3-bis((pentafluorophenyl)methyl)imidazole-2-ylidene) ligand was found to significantly acc

A mild Ni/Cu-catalyzed silylation via C -O cleavage

A Ni/Cu-catalyzed silylation of unactivated C-O electrophiles derived from phenols or benzyl alcohols is described. This transformation is characterized by its wide scope and mild conditions, providing a direct access to synthetically versatile silylated compounds. The protocol allows for the coupling of C(sp 2)-O and even C(sp3)-O bonds with similar efficiency.

Pd(II)-catalyzed C-H activation/aryl-aryl coupling of phenol esters

(Chemical Equation Presented) Although nitrogen-containing group-directed cyclopalladation reactions have been well-known, Pd(II) insertion into C-H bonds promoted by coordination of an oxygen-only group to the palladium remains rather rare. In the present study, the first cyclopalladation complex formed from a simple phenol ester was characterized by X-ray crystallography. A promising protocol for the ortho C-H activation/aryl-aryl coupling of phenol esters that was not sensitive to moisture or air was then established. The utility of the reaction was demonstrated for the synthesis of useful phenol derivatives. Copyright