97580-20-6Relevant articles and documents
α-HYDROXYALKYLATION OF HETEROAROMATIC BASES BY ALCOHOLS AND HYDROXYLAMINE-O-SULPHONIC ACID
Citterio, Attilio,Gentile, Anna,Minisci, Francesco,Serravalle, Marco,Ventura, Susanna
, p. 617 - 620 (1985)
The homolytic decomposition of hydroxylamine-O-sulphonic acid in alcoholic solvents was investigated in the presence or absence of protonated heteroaromatic bases and Fe(II) salt.THe addition of the α-hydroxyalkyl radicals to the base and their oxidation by Fe(III) salt to the corresponding alkyl cyanide were competitive processes.A redox chain process involving the amino radical cation NH3+, is suggested and the factors affecting the yields of the homolytic substitution are discussed.