99839-93-7

Basic information

• Product Name: N-methyl-N-phenyl-carbamoyl cyanide
• Synonyms: N-methyl-N-phenyl-carbamoyl cyanide
• CAS NO: 99839-93-7
• Molecular Weight: 160.175
• Mol File: 99839-93-7.mol
• Article Data: 13

Chemical Properties

• CAS DataBase Reference: N-methyl-N-phenyl-carbamoyl cyanide(CAS DataBase Reference)
• NIST Chemistry Reference: N-methyl-N-phenyl-carbamoyl cyanide(99839-93-7)
• EPA Substance Registry System: N-methyl-N-phenyl-carbamoyl cyanide(99839-93-7)

Safety Data

• Hazardous Substances Data: 99839-93-7(Hazardous Substances Data)

Upstream product

• 74-90-8 hydrogen cyanide 
• 4285-42-1 N-phenyl-N-methylcarbamoyl chloride 
• 1115-12-4 carbonyl cyanide 
• 100-61-8 N-methylaniline 
• 117873-02-6 (2Z,4E)-2-(N-methylanilino)-5-phenyl-2,4-pentadienenitrile 
• 117873-01-5 (2E,4E)-2-(N-methylanilino)-5-phenyl-2,4-pentadienenitrile 
• 19270-07-6 cyanoformic acid 
• 7677-24-9 trimethylsilyl cyanide 
• 92289-43-5 imidazole-1-carboxylic acid methylphenylamide 
• 93-61-8 N-methyl-N-phenylformamide 
• 545-06-2 trichloroacetonitrile 
• 2352-41-2 2-(hydroxyimino)-3-oxo-N-methyl-N-phenylbutanamide 
• 1228378-60-6 C₁₆H₁₆N₄O 
• 1029963-92-5 3-(1H-indol-3-yl)-2-azido-N-(2-iodophenyl)-N-methylpropanamide 

Relevant articles and documents

Electrochemical Synthesis of Cyanoformamides from Trichloroacetonitrile and Secondary Amines Mediated by the B12Derivative

The B12derivative, heptamethyl cobyrinate, -mediated electrochemical synthesis of cyanoformamides has been developed. Aerobic oxygenation of the carbon-centered radical initiatedin situgeneration of the reactive acyl chloride intermediate, whic

Transition-Metal-Free Conversion of Trifluoropropanamides into Cyanoformamides through C-CF3 Bond Cleavage and Nitrogenation

A new transition-metal-free transformation of trifluoropropanamides into cyanoformamides through a sequence of C-CF3 bond cleavage and nitrogenation using tert-butyl nitrite as the nitrogen source is described. The method features direct detrifluoromethylation, broad substrate scopes, and excellent selectivity control, representing a new shortcut for constructing the nitrile group involving C-CF3 σ-bond cleavage.

Synthesis of 2-oxindoles via 'transition-metal-free' intramolecular dehydrogenative coupling (IDC) of sp2 C-H and sp3 C-H bonds

The synthesis of a variety of 2-oxindoles bearing an all-carbon quaternary center at the pseudo benzylic position has been achieved via a 'transition-metal-free' intramolecular dehydrogenative coupling (IDC). The construction of 2-oxindole moieties was carried out through formation of carbon-carbon bonds using KOt-Bu-catalyzed one pot C-alkylation of β-N-arylamido esters with alkyl halides followed by a dehydrogenative coupling. Experimental evidences indicated toward a radical-mediated path for this reaction.