On the regioselectivity of the nucleophilic aromatic photosubstitution of 4-Nitroanisole (cas 100-17-4). A dual mechanistic pathway
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Add time:07/27/2019 Source:sciencedirect.com
4-Nitroanisole photoreacts with n-hexylamine and ethyl glycinate giving rise to regioselective methoxy and nitro group photosubstitutions respectively. Mechanistic evidences indicate the last is produced through a SN23Ar* reaction whereas the first arises from a radical ion pair via electron transfer from the amine to a 4-nitroanisole triplet excited state.
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