Fluoro(trimethyl)stannane

Base Information

• Chemical Name: Fluoro(trimethyl)stannane
• CAS No.: 420-60-0
• Molecular Formula: C3H9FSn
• Molecular Weight: 182.813
• Hs Code.: 2931900090
• DSSTox Substance ID: DTXSID70472114
• Mol file: 420-60-0.mol

Synonyms:fluoro(trimethyl)stannane;420-60-0;Stannane, fluorotrimethyl-;TRIMETHYLTIN FLUORIDE;Me3SnF;FLUOROTRIMETHYLSTANNANE;DTXSID70472114

Chemical Property of Fluoro(trimethyl)stannane

Chemical Property:

• Melting Point: 375°C dec
• PSA: 0.00000
• LogP: 1.79080
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 0
• Exact Mass: 183.971031
• Heavy Atom Count: 5
• Complexity: 28.4

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C[Sn](C)(C)F

Technology Process of Fluoro(trimethyl)stannane

There total 11 articles about Fluoro(trimethyl)stannane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

xenon difluoride (13709-36-9) + p-(ethoxycarbonyl)phenylselenotrimethylstannane (284043-22-7) + hex-3-yne (928-49-4) → trimethyltin fluoride (420-60-0) + (E)-3-[(p-ethoxycarbonyl)phenylseleno]-4-fluorohex-3-ene (181075-89-8)

Guidance literature:

In dichloromethane; XeF2 added in small portions under Ar to a soln. of selenide in CH2Cl2 at -20°C, stirred for 30 min, the acetylene added, stirred for 1 h at -20°C and for 1 h at room temp.; precipitate separated, washed with n-pentane, solvent removed under vacuum, crude product purified by column chromy., elem. anal.;

DOI:10.1002/(SICI)1099-0682(200006)2000:6<1307::AID-EJIC1307>3.3.CO;2-Q

Reference yield: 96.0%

xenon difluoride (13709-36-9) + 4-Octyne (1942-45-6) + trimethylstannyl phenyl selenide (4848-71-9) → (E)-4-fluoro-5-(phenylseleno)oct-4-ene (129053-33-4) + trimethyltin fluoride (420-60-0)

Guidance literature:

In dichloromethane; XeF2 added in small portions under Ar to a soln. of selenide in CH2Cl2 at -20°C, stirred for 30 min, the acetylene added, stirred for 1 h at -20°C and for 1 h at room temp.; precipitate separated, washed with n-pentane, solvent removed under vacuum, crude product purified by column chromy., elem. anal.;

DOI:10.1002/(SICI)1099-0682(200006)2000:6<1307::AID-EJIC1307>3.3.CO;2-Q

Reference yield: 78.0%

tetramethylstannane (594-27-4) → trimethyltin fluoride (420-60-0) + dimethyltin difluoride (3582-17-0)

Guidance literature:

anhydrous HF, HF : Sn(CH3)4 = 142 : 1, 130°C, 4h;

upstream raw materials:

trimethylstannylbis(trifluoromethyl)arsane

trimethyl(trifluoromethyl)tin

trimethylstannane

di-(perfluoro vinyl) dimethyl stannane

Downstream raw materials:

tetramethylstannane

titanocene difluoride

phosphorus pentafluoride

trimethyltin(IV)chloride

Refernces

• 1、 Grobe, Joseph,Van, Duc Le. "Einfache Synthese von Heteroalkenen CF3E=CF2 (E=P, As)". . p. 716 - 717. Retrieved 2007/10/02.
• 2、 Cullen,Sams,Waldman. "Preparation and properties of some fluorocarbon derivatives of tin". . p. 1682 - 1686. Retrieved 2007/10/06.