Benzene, 1,1'-(1,2-ethanediyl)bis[4-ethenyl-

Base Information

• Chemical Name: Benzene, 1,1'-(1,2-ethanediyl)bis[4-ethenyl-
• CAS No.: 48174-52-3
• Molecular Formula: C18H18
• Molecular Weight: 234.341
• DSSTox Substance ID: DTXSID80453919
• Nikkaji Number: J760.438F
• Wikidata: Q82275213
• Mol file: 48174-52-3.mol

Synonyms:48174-52-3;1,2-Bis(4-vinylphenyl)ethane;p,p'-Divinyl-1,2-diphenylethane;1-ethenyl-4-[2-(4-ethenylphenyl)ethyl]benzene;Benzene, 1,1'-(1,2-ethanediyl)bis[4-ethenyl-;1,2-bis(p-vinylphenyl)ethane;DTXSID80453919;ZXLAFQNTMMFLSA-UHFFFAOYSA-N;F87990

Chemical Property of Benzene, 1,1'-(1,2-ethanediyl)bis[4-ethenyl-

Chemical Property:

• XLogP3: 5.7
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 5
• Exact Mass: 234.140850574
• Heavy Atom Count: 18
• Complexity: 221

Purity/Quality:

95% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C=CC1=CC=C(C=C1)CCC2=CC=C(C=C2)C=C

Technology Process of Benzene, 1,1'-(1,2-ethanediyl)bis[4-ethenyl-

There total 11 articles about Benzene, 1,1'-(1,2-ethanediyl)bis[4-ethenyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

4-Vinylbenzyl chloride (1592-20-7,29296-32-0) → 1,2-bis(4-vinylphenyl)-ethane (48174-52-3)

Guidance literature:

With iodine; magnesium; In tetrahydrofuran; for 12h; Reflux;

DOI:10.1002/pola.24139

Reference yield:

1,2-bis[4-(1-hydroxyethyl)phenyl]ethane (38147-31-8) → 1,2-bis(4-vinylphenyl)-ethane (48174-52-3)

Guidance literature:

With 4-tert-Butylcatechol; toluene-4-sulfonic acid; In o-xylene; at 144 ℃; for 1.83333h;

DOI:10.1134/S1070427211100181

Reference yield:

(4-vinylbenzyl)magnesium chloride (87532-75-0) → docosanedioic acid (505-56-6) + 1,2-bis(4-vinylphenyl)-ethane (48174-52-3) + 12-(4-vinylphenyl)dodecanoic acid (119011-64-2)

Guidance literature:

With dilithium tetrachlorocuprate; 11-bromoundecanoic acid; ethylmagnesium bromide; In tetrahydrofuran; diethyl ether; Title compound not separated from byproducts; 1.) from -25 to -20 deg C, 2.) -20 deg C, 1.5 h;

DOI:10.1021/jo00269a038

upstream raw materials:

11-bromoundecanoic acid

(4-vinylbenzyl)magnesium chloride

bis(4-vinylphenylmethyl)selenide

bis(4-vinylphenylmethyl)sulfide

Refernces

• 1、 Heigl,Greiderer,Petter,Kolomiets,Siesler,Ulbricht,Bonn,Huck. "Simultaneous determination of the micro-, meso-, and macropore size fractions of porous polymers by a combined use of fourier transform near-infrared diffuse reflection spectroscopy and multivariate techniques". . p. 8493 - 8500. Retrieved 2008.
• 2、 Zaitsev,Shvabskaya. "Divinyl aromatic compounds and Di(methacrylates) prepared by acid-catalyzed transformations of bis[4-(1-hydroxyethyl)phenyl]alkanes". experimental part. p. 1783 - 1794. Retrieved 2012/02/15.