109466-24-2Relevant articles and documents
Oxidant-Free Selective Synthesis of Functionalized Chroman-4-ones from ortho -Hydroxyacetophenones under HOAc/DMSO Conditions
Feng, Yuanyuan,Jiang, Tao-Shan,Li, Shuai,Shi, Xu,Wang, Anan
, (2022/02/10)
A metal-free and oxidant-free acid-promoted DMSO activation and subsequent reaction is reported. In this protocol, two molecules of DMSO are activated by HOAc and serve as dual synthons which react with ortho-hydroxyacetophenones, affording 3-(methylthiomethyl)chroman-4-ones in moderate to good yields with high selectivity.
Reactivite de β-enaminones cycliques. II. Cyclocondensation directe d'amidines, d'hydrazines et de l'hydroxylamine sur la pyrrolidinomethylene-3 chromanone-4
Graffe, Bernadette,Sacquet, Marie-Claude,Bellassoued-Fargeau, Marie-Claude,Maitte, Pierre
, p. 1753 - 1756 (2007/10/02)
The reaction of pyrrolidinomethylenechromanone 1 with guanidine and amidines gave benzopyrannopyrimidines 5 in good yields.Treatment of enaminone 1 with hydroxylamine in the presence of hydrochloric acid afforded the isoxazole 9.When hydrazine and phenylh