112671-40-6Relevant articles and documents
Iridium-Catalyzed Isomerization/Cycloisomerization/Aromatization of N-Allyl-N-sulfonyl-o-(λ1-silylethynyl)aniline Derivatives to Give Substituted Indole Derivatives
Arisawa, Mitsuhiro,Matsuzaki, Tsuyoshi,Murai, Kenichi,Ohno, Shohei,Qiu, Jiawei,Sako, Makoto,Suzuki, Takeyuki,Takehara, Tsunayoshi,Tanaka, Tomoyuki
supporting information, p. 4284 - 4288 (2021/06/28)
We have developed a one-iridium-catalyst system that transforms N-allyl-N-sulfonyl-2-(silylalkynyl)aniline derivatives, which are 1,7-enynes in which both multiple bonds have a heteroatom, to the corresponding substituted indole derivatives via isomerizat
Ruthenium-Catalyzed 1,6-Aromatic Enamide-Silylalkyne Cycloisomerization: Approach to 2,3-Disubstituted Indoles
Takamoto, Kohei,Ohno, Shohei,Hyogo, Norimichi,Fujioka, Hiromichi,Arisawa, Mitsuhiro
, p. 8733 - 8742 (2017/08/23)
Cycloisomerization is an atom economic procedure that converts dienes and enynes into cyclic molecules. To date, cycloisomerization between enamides and silylalkynes has not been explored. We found that N-acyl-N-vinyl-2-silylalkynylaniline derivatives und
Cascades to substituted indoles
Rainier, Jon D.,Kennedy, Abigail R.
, p. 6213 - 6216 (2007/10/03)
This paper describes the synthesis of dithioindoles from the free-radical cyclizations of arylisonitriles having pendant alkynes. Also described is the synthesis of substituted indoles and spiro-fused indoles from the coupling of dithioindoles with active hydrogen-containing compounds.
