130970-51-3

Basic information

• Product Name: 1,4-Cyclohexanediol, 2,5-bis(1-methylethyl)-, dimethanesulfonate,(1S,2R,4S,5R)-
• Synonyms: 1,4-Cyclohexanediol, 2,5-bis(1-methylethyl)-, dimethanesulfonate,(1S,2R,4S,5R)-
• CAS NO: 130970-51-3
• Molecular Formula: C14H28O6S2
• Molecular Weight: 356.505
• Mol File: 130970-51-3.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: 1,4-Cyclohexanediol, 2,5-bis(1-methylethyl)-, dimethanesulfonate,(1S,2R,4S,5R)-(CAS DataBase Reference)
• NIST Chemistry Reference: 1,4-Cyclohexanediol, 2,5-bis(1-methylethyl)-, dimethanesulfonate,(1S,2R,4S,5R)-(130970-51-3)
• EPA Substance Registry System: 1,4-Cyclohexanediol, 2,5-bis(1-methylethyl)-, dimethanesulfonate,(1S,2R,4S,5R)-(130970-51-3)

Safety Data

• Hazardous Substances Data: 130970-51-3(Hazardous Substances Data)

Upstream product

• 114300-89-9 1,4-diisopropyl-1,4-cyclohexadiene 
• 131063-58-6 (1S,2R,4S,5R)-(+)-2,5-diisopropylcyclohexane-1,4-diol 
• 124-63-0 methanesulfonyl chloride 

Downstream Products

• 22907-72-8 1,4-diisopropylcyclohexane 
• 131063-58-6 (1S,2R,4S,5R)-(+)-2,5-diisopropylcyclohexane-1,4-diol 
• 100-18-5 1,4-bis(1-methylethyl)benzene 

Relevant articles and documents

Syntheses of Novel Chiral Monophosphines, 2,5-Dialkyl-7-phenyl-7-phosphabicycloheptanes, and Their Application in Highly Enantioselective Pd-Catalyzed Allylic Alkylation

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Chiral Bicyclo[2.2.2]octane-Fused CpRh Complexes: Synthesis and Potential Use in Asymmetric C?H Activation

A new class of chiral cyclopentadienyl rhodium(I) complexes (CpRhI) bearing C2-symmetric chiral bridged-ring-fused Cp ligands was prepared. The complexes were successfully applied to the asymmetric C?H activation reaction of N-methoxybenzamides with quinones, affording a series of chiral hydrophenanthridinones in up to 82 % yield with up to 99 % ee. Interestingly, structure analysis reveals that the side wall of the optimal chiral CpRhI catalyst is vertically more extended, horizontally less extended, and closer to the metal center in comparison with the classic binaphthyl and spirobiindanyl CpRhI complexes, and may thus account for its superior catalytic performance.

Syntheses of novel chiral 2,5-dialkyl-7-azabicyclo[2.2.1]heptanes and 2,5-dialkyl-7-thiobicyclo[2.2.1]heptanes

New C2-symmetric chiral amines with a rigid bicyclic framework have been synthesized via hydrogenation of monoazides catalyzed by 5% Pd/C in methanol. Enantiomerically pure 2,5-dialkyl-7-thiobicyclo[2.2.1]heptanes were made from readily available materials.