131063-58-6

Basic information

• Product Name: (1S,2R,4S,5R)-(+)-2,5-diisopropylcyclohexane-1,4-diol
• Synonyms: (1S,2R,4S,5R)-(+)-2,5-diisopropylcyclohexane-1,4-diol
• CAS NO: 131063-58-6
• Molecular Weight: 200.321
• Mol File: 131063-58-6.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: (1S,2R,4S,5R)-(+)-2,5-diisopropylcyclohexane-1,4-diol(CAS DataBase Reference)
• NIST Chemistry Reference: (1S,2R,4S,5R)-(+)-2,5-diisopropylcyclohexane-1,4-diol(131063-58-6)
• EPA Substance Registry System: (1S,2R,4S,5R)-(+)-2,5-diisopropylcyclohexane-1,4-diol(131063-58-6)

Safety Data

• Hazardous Substances Data: 131063-58-6(Hazardous Substances Data)

Upstream product

• 114300-89-9 1,4-diisopropyl-1,4-cyclohexadiene 
• 1079104-45-2 (1S,2R,4S,5R)-1,4-di-d-camphorosulfonato-2,5-diisopropylcyclohexane 
• 130970-51-3 (1S,2R,4S,5R)-2,5-diisopropylcyclohexane-1,4-diyl dimethanesulfonate 
• 100-18-5 1,4-bis(1-methylethyl)benzene 
• 22907-72-8 1,4-diisopropylcyclohexane 

Downstream Products

• 130970-51-3 (1S,2R,4S,5R)-2,5-diisopropylcyclohexane-1,4-diyl dimethanesulfonate 

Relevant articles and documents

Synthesis of optically active 2,5-dialkylcyclohexane-1,4-diols and their application in the asymmetric oxidation of sulfides

A simple and efficient approach to obtain optically pure 1,4-diols was established. The asymmetric oxidation of sulfides to sulfoxides with cumyl hydroperoxide in moderate yields and moderate to high enantioselectivities (up to 84%) catalyzed by chiral Ti/ 1,4-diols complexes has been achieved. A 76% ee value was obtained in the asymmetric synthesis of esomeprazole. Georg Thieme Verlag Stuttgart.

Syntheses of novel chiral 2,5-dialkyl-7-azabicyclo[2.2.1]heptanes and 2,5-dialkyl-7-thiobicyclo[2.2.1]heptanes

New C2-symmetric chiral amines with a rigid bicyclic framework have been synthesized via hydrogenation of monoazides catalyzed by 5% Pd/C in methanol. Enantiomerically pure 2,5-dialkyl-7-thiobicyclo[2.2.1]heptanes were made from readily available materials.