13112-46-4

Basic information

• Product Name: Benzene, 1,1'-[(phenylthio)ethenylidene]bis-
• CAS NO: 13112-46-4
• Molecular Formula: C20H16S
• Molecular Weight: 288.413
• Mol File: 13112-46-4.mol
• Article Data: 20

Chemical Properties

• CAS DataBase Reference: Benzene, 1,1'-[(phenylthio)ethenylidene]bis-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1,1'-[(phenylthio)ethenylidene]bis-(13112-46-4)
• EPA Substance Registry System: Benzene, 1,1'-[(phenylthio)ethenylidene]bis-(13112-46-4)

Safety Data

• Hazardous Substances Data: 13112-46-4(Hazardous Substances Data)

Upstream product

• 119-61-9 benzophenone 
• 17873-08-4 (phenylsulfanylmethyl)trimethylsilane 
• 66080-23-7 4,4,5,5-tetramethyl-2-((phenylsulfanyl)methyl)-1,3,2-dioxaborolane 
• 13307-63-6 α,α-Diphenyl-α-hydroxy-acetaldehyd-diphenylthioacetal 
• 530-48-3 1,1-Diphenylethylene 
• 931-59-9 benzenesulfenyl chloride 
• 13249-58-6 1-bromo-2,2-diphenylethylene 
• 3111-52-2 potassium thiophenolate 
• 65267-08-5 bis(2,2-diphenylvinyl)mercury 
• 882-33-7 diphenyldisulfane 
• 19997-66-1 1-iodo-2,2-diphenylethylene 
• 21514-24-9 mercury thiophenolate 
• 98-09-9 benzenesulfonyl chloride 
• 873-55-2 sodium benzenesulfonate 

Downstream Products

• 882-33-7 diphenyldisulfane 
• 737-79-1 1,1,3,-triphenyl-1-propene 
• 120677-82-9 (C₆H₅)2CCH(Sn(C₆H₅)3) 
• 120677-76-1 (2,2-diphenyl)ethenyltriphenylgermane 
• 120677-77-2 (C₆H₅)2CCH(Ge(CH(CH₃)2)3) 
• 91083-83-9 1-cyclohexyl-2,2’-diphenylethene 
• 35467-39-1 1,1-diphenyl-3-methylbutene 
• 612-00-0 1,1'-ethylidenebis-benzene 
• 3019-20-3 isopropylthiobenzene 

Relevant articles and documents

Electrochemistry Enabled Nickel-Catalyzed Selective C?S Bond Coupling Reaction

This work describes an electrochemical enabled nickel-catalyzed chemoselective C?S bond coupling protocol for the production of aryl sulfides and sulfones. By simply switching the nickel catalysts and electrodes, this electrochemical C?S bond coupling has demonstrated excellent redox activity, scalability and sustainability. Furthermore, the mechanism for this electrochemical cross-coupling reaction has been investigated.

Palladium-Catalyzed Picolinamide-Directed Benzylic C(sp3)?H Chalcogenation with Diaryl Disulfides and Diphenyl Diselenide

The first palladium-catalyzed direct benzylic C(sp3)?H chalcogenation with diaryl disulfides and diphenyl diselenide has been established. The coupling reaction proceeds between the thioether radical and palladiumcycle intermediate. Picolinamide serves as an excellent directing group for the C?H activation of benzylic C(sp3)?H and can be easily removed. The current protocol exhibits a relatively broad substrate scope and high functional group compatibility. A mechanistic study indicates that palladium(IV) intermediate is probably formed during the course of the reaction. (Figure presented.).