35467-39-1

Basic information

• Product Name: Benzene, 1,1'-(3-methyl-1-butenylidene)bis-
• CAS NO: 35467-39-1
• Molecular Formula: C17H18
• Molecular Weight: 222.33
• Mol File: 35467-39-1.mol
• Article Data: 20

Chemical Properties

• CAS DataBase Reference: Benzene, 1,1'-(3-methyl-1-butenylidene)bis-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1,1'-(3-methyl-1-butenylidene)bis-(35467-39-1)
• EPA Substance Registry System: Benzene, 1,1'-(3-methyl-1-butenylidene)bis-(35467-39-1)

Safety Data

• Hazardous Substances Data: 35467-39-1(Hazardous Substances Data)

Upstream product

• 556-24-1 methyl 3-methylbutanoate 
• 119-61-9 benzophenone 
• 19997-66-1 1-iodo-2,2-diphenylethylene 
• 30615-19-1 isopropylmercury(II) chloride 
• 33795-03-8 2,2-dimethyl-1,4,4-triphenylbut-3-en-1-one 
• 26189-62-8 phenyl 2,2-diphenylethenyl sulfone 
• 13112-46-4 2,2-diphenyl-1-phenylthioethene 
• 2397-67-3 triisopropylaluminium 
• 67341-86-0 Ph₂CCHHgBr 
• 5820-02-0 2,2-dimethyl-4,4-diphenyl-but-3-enal 
• 530-48-3 1,1-Diphenylethylene 
• 78-84-2 isobutyraldehyde 
• 26466-27-3 (3-methylbutane-1,1-diyl)dibenzene 
• 1539-32-8 4-isopropyl-2,6-dimethyl-1,4-dihydro-pyridine-3,5-dicarboxylic acid diethyl ester 

Downstream Products

• 88074-05-9 C₁₈H₁₈Cl₂ 
• 33830-03-4 2.2-Dibromo-1.1-diphenyl-3-isopropylcyclopropan 
• 32134-41-1 1,1'-(2,2-dimethylcyclopropylidene)bis(benzene) 
• 99943-04-1 2-acetoxy-3-methyl-1,1-diphenylbutan-1-ol 
• 22133-84-2 2-bromo-1,1-diphenyl-3-methylbutene 
• 1380439-66-6 (3-methylbut-1-ene-1,1,2-triyl)tribenzene 

Relevant articles and documents

Visible-light-mediated alkylation of 4-alkyl-1,4-dihydropyridines with alkenyl sulfones

Herein we report a mild, general protocol for visible-light-mediated alkylation of 4-alkyl-1,4-dihydropyridines with alkenyl sulfones. The protocol permits efficient functionalization of sulfones with a broad range of cyclic and acyclic secondary and tert

RETRACTED ARTICLE: Copper-Catalyzed Decarboxylative C(sp2)-C(sp3) and C(sp)-C(sp3) Coupling of Substituted Cinnamic Acids and 3-Phenyl Propiolic Acid with N-Tosyl Oxaziridines

A mild and efficient strategy for decarboxylative C(sp2)-C(sp3) and C(sp)-C(sp3) coupling of α,β-unsaturated carboxylic acids such as substituted cinnamic acids and 3-phenyl propiolic acid with N-Tosyl oxaziridines was developed. The corresponding products were achieved in moderate to good yields with excellent stereoselectivity. Base-free and oxidant-free conditions allow good functional group tolerance. Radical inhibitors such as TEMPO and BHT completely suppressed the reactions suggesting a radical mechanism was involved. This study is supposed to broaden the frontier of oxaziridines' chemistry and to open up a novel cascade for alkylating reagents.

Triarylalkenes from the site-selective reductive cross-coupling of benzophenones and aldehydes

PhP(Li)TMS converts benzophenones to phosphaalkenes which upon activation under oxidizing, basic conditions react with aromatic aldehydes under the formation of triarylalkenes. The one-pot reaction omits transition metals, proceeds at room temperature and precludes the formation of any homo-coupling products. Systematic substrate variations reveal reactivity patterns that are useful for the identification of ketone/aldehyde combinations that can be coupled in yields up to 80%.