13509-27-8

Basic information

• Product Name: METHYL PHENYL CARBONATE
• Synonyms: PHENYLMETHYL CARBONATE;METHYL PHENYL CARBONATE;Carbonic acid methyl phenyl;Carbonic acid O-phenyl O-methyl ester;Carbonic acid=methyl=phenyl ester
• CAS NO: 13509-27-8
• Molecular Formula: C₈H₈O₃
• Molecular Weight: 152.15
• Mol File: 13509-27-8.mol
• Article Data: 83

Chemical Properties

• Melting Point: 147-151 °C
• Boiling Point: 210-213℃
• Flash Point: 97.1 °C
• Appearance: colourless liquid
• Density: 1.14 g/cm³
• Vapor Pressure: 0.124mmHg at 25°C
• Refractive Index: 1.4985
• Storage Temp.: Inert atmosphere,Room Temperature
• Stability: Stable. Incompatible with strong oxidizing agents.
• CAS DataBase Reference: METHYL PHENYL CARBONATE(CAS DataBase Reference)
• NIST Chemistry Reference: METHYL PHENYL CARBONATE(13509-27-8)
• EPA Substance Registry System: METHYL PHENYL CARBONATE(13509-27-8)

Safety Data

• Safety Statements: 22-24/25
• Hazardous Substances Data: 13509-27-8(Hazardous Substances Data)

Usage

Chemical Properties

colourless liquid

InChI:InChI=1/C8H8O3/c1-10-8(9)11-7-5-3-2-4-6-7/h2-6H,1H3

Upstream product

• 102-09-0 bis(phenyl) carbonate 
• 67-56-1 methanol 
• 108-95-2 phenol 
• 90731-95-6 3-Chloro-4-phenyl-4H-pyridine-1-carboxylic acid phenyl ester 
• 4382-72-3 methoxymethyl chloroacetate 
• 154027-21-1 2-methoxy-5,5-dimethyl-2-phenoxy-Δ³-1,3,4-oxadiazoline 
• 616-38-6 carbonic acid dimethyl ester 
• 17175-16-5 p-nitrophenyl methyl carbonate 
• 6099-87-2 methyl 2,4-dinitrophenyl carbonate 
• 138835-54-8 2,4,6-trinitrophenyl methyl carbonate 
• 201230-82-2 carbon monoxide 
• 107-31-3 Methyl formate 
• 122-79-2 Phenyl acetate 
• 124-38-9 carbon dioxide 

Downstream Products

• 17175-16-5 p-nitrophenyl methyl carbonate 
• 6132-41-8 carbonic acid methyl ester-(2-nitro-phenyl ester) 
• 2603-10-3 N-phenyl methyl carbamate 
• 591-40-2 Anilinium-triflourmethansulfonat 
• 5817-70-9 methyl N-benzylcarbamate 
• 93-99-2 benzoic acid phenyl ester 
• 102-09-0 bis(phenyl) carbonate 
• 2555-49-9 phenoxyacetic acid ethyl ester 
• 2486-07-9 2,4-dinitrophenyl phenyl ether 
• 1245824-37-6 C₁₄H₁₉BO₅ 
• 103-82-2 phenylacetic acid 
• 67-56-1 methanol 
• 108-95-2 phenol 
• 4277-63-8 methyl 1H-pyrrole-1-carboxylate 

Related news

Isobaric vapor–liquid equilibrium at 101.3 kPa and excess properties at 298.15 K for binary mixtures of METHYL PHENYL CARBONATE (cas 13509-27-8) with methanol or dimethyl carbonate08/13/2019

The vapor pressure of the pure component of methyl phenyl carbonate (MPC) was measured at temperatures ranging from 378 K to 488 K. The experimental vapor pressures could be fit well with a three-parameter Antoine equation. Isobaric vapor–liquid equilibria for binary systems (MPC + methanol and...detailed

Preparation and catalytic property of MoO3/SiO2 for disproportionation of METHYL PHENYL CARBONATE (cas 13509-27-8) to diphenyl carbonate08/12/2019

MoO3/SiO2 were prepared by different methods and used as heterogeneous catalysts for the liquid-phase disproportionation of methyl phenyl carbonate (MPC) to diphenyl carbonate (DPC). The characterization of XRD, FT-IR and BET showed that the preparation methods remarkably affected the structural...detailed

Efficient synthesis of 1,6-hexamethylene diurethane through coupling transesterification and methoxycarbonylation with METHYL PHENYL CARBONATE (cas 13509-27-8) as intermediate08/11/2019

A reaction coupling system of transesterification and methoxycarbonylation with methyl phenyl carbonate (MPC) as intermediate was established to efficiently prepare 1,6-hexamethylene diurethane (HDU) from 1,6-hexamethylene diamine (HDA). The feasibility of the system was explored using the therm...detailed

Highly efficient and stable PbO–ZrO2 catalyst for the disproportionation of METHYL PHENYL CARBONATE (cas 13509-27-8) to synthesize diphenyl carbonate08/10/2019

Heterogeneous PbO–ZrO2 catalysts (PbZr) were first prepared by coprecipitation method, and used to catalyze the liquid-phase disproportionation reaction of methyl phenyl carbonate (MPC) to synthesize diphenyl carbonate (DPC). PbZr with PbO loading of 15.2 wt% (15.2PbZr) exhibited the best catal...detailed

Influence of coordination groups on the catalytic performances of organo-titanium compounds for disproportionation of METHYL PHENYL CARBONATE (cas 13509-27-8) to synthesize diphenyl carbonate08/09/2019

The disproportionation of methyl phenyl carbonate (MPC) to synthesize diphenyl carbonate (DPC) catalyzed by organo-titanium compounds with different coordination groups was systematically investigated. The results of the molecular structure analysis, the catalytic performance evaluation and the ...detailed

A study of METHYL PHENYL CARBONATE (cas 13509-27-8) and diphenyl carbonate as electrolyte additives for high voltage LiNi0.8Mn0.1Co0.1O2/graphite pouch cells08/08/2019

The effectiveness of methyl phenyl carbonate and diphenyl carbonate as electrolyte additives either singly or in combination with methylene methyl disulfonate and tris(-trimethyl-silyl)-phosphite has been systematically investigated in LiNi0.8Mn0.1Co0.1O2/graphite pouch cells. Experiments conduc...detailed

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Methylchloroformate synthesis via direct interaction of palladium di(methoxycarbonyl) complexes with CuCl2: utilization in the synthesis of carbonates and carbamates

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Proton Inventories of the Basic Methanolysis of Phenyl Methyl Carbonate and Diphenyl Carbonate

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Diphenyl carbonate compound preparation method

The invention relates to the field of diphenyl carbonate synthesis, and discloses a diphenyl carbonate compound preparation method, which comprises: in the presence of a catalyst represented by a formula (1-1) or a formula (1-2), carrying out a transesterification reaction on a phenol compound represented by a formula (II) and a diester carbonate compound represented by a formula (III), wherein R1, R2 and R3 are selected from a C1-C14 aliphatic hydrocarbon group, a C3-C14 cycloalkyl group, a C6-C14 aryl group, a C7-C14 alkylaryl group, a C7-C14 aralkyl group and a C10-C14 condensed ring aryl group, and X is halogen. The method is high in catalytic activity, high in selectivity and good in stability. Formula (1-1) is (H-[O-Si-(R1)2]n-O)x1-Ti-(OR3)y1X(4-x1-y1), and formula (1-2) is [Si(R2)xO]x2-Ti-(OR3)y2X(4-x2-y2).