1401429-99-9

Basic information

• Product Name: C₁₈H₁₉BrN₂S
• Synonyms: C₁₈H₁₉BrN₂S
• CAS NO: 1401429-99-9
• Molecular Weight: 375.332
• Mol File: 1401429-99-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: C₁₈H₁₉BrN₂S(CAS DataBase Reference)
• NIST Chemistry Reference: C₁₈H₁₉BrN₂S(1401429-99-9)
• EPA Substance Registry System: C₁₈H₁₉BrN₂S(1401429-99-9)

Safety Data

• Hazardous Substances Data: 1401429-99-9(Hazardous Substances Data)

Upstream product

• 1218756-12-7 3-(2-bromobenzyl)-1-butyl-1H-benzo[d]imidazol-3-ium bromide 
• 4886-30-0 1-butylbenzimidazole 
• 51-17-2 benzoimidazole 

Relevant articles and documents

Facile synthesis of benzimidazolin-2-chalcogenones: Nature of the carbon-chalcogen bond

A new method using chalcogen nucleophiles E2-/E2 2- (E = S, Se, Te) for the convenient and high yield synthesis of benzimidazolin-2-chalcogenones has been developed. The reaction of strong nucleophiles E2-/E22- with various benzimidazolium salts under mild conditions afforded benzimidazolin-2- chalcogenones (10a-10g) in better yield compared to the other methods involving E0 powder. Benzimidazolin-2-tellurones were found to be unstable when pyridyl/phenyl groups were bonded to one of the nitrogens of the benzimidazolium salts and the reaction led to the isolation of the corresponding diamines (12a and 12b). The selenones/tellurones could be easily oxidized to the corresponding dihaloderivatives (16a-16e) by the reaction of the chalcogenones with bromine/iodine. The nature of the carbon-chalcogen double bond has been investigated with the help of single crystal X-ray, NMR spectroscopy and Density Functional Theory (DFT) calculations.