141362-07-4

Basic information

• Product Name: Naphthalene, 1-[2-(methoxymethoxy)phenyl]-
• CAS NO: 141362-07-4
• Molecular Formula: C18H16O2
• Molecular Weight: 264.324
• Mol File: 141362-07-4.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: Naphthalene, 1-[2-(methoxymethoxy)phenyl]-(CAS DataBase Reference)
• NIST Chemistry Reference: Naphthalene, 1-[2-(methoxymethoxy)phenyl]-(141362-07-4)
• EPA Substance Registry System: Naphthalene, 1-[2-(methoxymethoxy)phenyl]-(141362-07-4)

Safety Data

• Hazardous Substances Data: 141362-07-4(Hazardous Substances Data)

Upstream product

• 824-91-9 O-methoxymethylphenol 
• 90-13-1 1-Chloronaphthalene 
• 108-95-2 phenol 
• 90-11-9 1-Bromonaphthalene 

Downstream Products

• 141362-13-2 1-(2-trifluormethanesulfonyloxyphenyl)naphthalene 
• 206-44-0 fluoranthene 
• 101277-90-1 1-(2′-hydroxyphenyl)naphthalene 

Relevant articles and documents

Benzo/Naphtho-Anellated Dihydro-1,2-oxaphosphinines and Ring-Opening to P-Tertiary 2-Phosphanyl-1,1′-biaryl-2-ol Derivatives – Syntheses and Structures

Reaction of naphthylphenol 1a and phenylnaphthol 1b, respectively, with PCl3 in the presence of ZnCl2 gave mixed benzo- and naphtho-anellated 6-chloro-6H-1,2-oxaphosphinines 2a and 2b. Treatment with equimolar amounts of tBuLi led to

Catalytic direct cross-coupling of organolithium compounds with aryl chlorides

Palladium-catalyzed direct cross-coupling of aryl chlorides with a wide range of (hetero)aryl lithium compounds is reported. The use of Pd-PEPPSI-IPent or Pd2(dba)3/XPhos as the catalyst allows for the preparation of biaryl and heterobiaryl compounds in high yields under mild conditions (room temperature to 40 C) with short reaction times.

A Palladium-Catalyzed Intramolecular Arene-Triflate Coupling for the Synthesis of Fluoranthrenes and Benzofluoranthrenes

A method for the preparation of fluoranthrenes and benzofluoranthrenes from aryl bromides and aryl methoxymethyl ethers is described.The key step in this synthesis is an intramolecular triflate-arene coupling mediated by bis(triphenylphosphine)palladium(II)chloride.Fluoranthrene, benzofluoranthrene, benzofluoranthrene, and indenopyrene were prepared in yields of 84-91percent.The regiospecific synthesis of substituted benzofluoranthrenes was demonstrated by the preparation of 6-fluorobenzofluoranthrene (72percent yield) and 5- and 6-methoxybenzofluoranthrene in yields of 73percent and 62percent respectively when the reaction was conducted in the presence of excess triphenylphosphine.Key Words: synthesis; palladium; triflate; fluoranthrene; benzofluoranthrene