1454-59-7

Basic information

• Product Name: 1-Hexanone, 1,3-diphenyl-
• CAS NO: 1454-59-7
• Molecular Formula: C18H20O
• Molecular Weight: 252.356
• Mol File: 1454-59-7.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: 1-Hexanone, 1,3-diphenyl-(CAS DataBase Reference)
• NIST Chemistry Reference: 1-Hexanone, 1,3-diphenyl-(1454-59-7)
• EPA Substance Registry System: 1-Hexanone, 1,3-diphenyl-(1454-59-7)

Safety Data

• Hazardous Substances Data: 1454-59-7(Hazardous Substances Data)

Usage

Physical form

White crystalline powder

Solubility

Insoluble in water, soluble in organic solvents

Common uses

Photoinitiator in the production of polymers (adhesives, coatings, plastics), intermediate in the synthesis of pharmaceuticals and organic compounds, production of fragrances and flavorings

Stability

Relatively stable

Toxicity

Low toxicity, suitable for industrial and commercial uses

Upstream product

• 42925-43-9 1-phenyl-2-hexen-1-one 
• 2633-57-0 triallyl(phenyl)silane 
• 3262-89-3 triphenylboroxine 
• 42925-43-9 (E)-1-phenylhex-2-en-1-one 
• 94-41-7 benzalacetophenone 
• 780-69-8 triethoxyphenylsilane 
• 14371-10-9 (E)-3-phenylpropenal 
• 106-94-5 propyl bromide 
• 591-51-5 phenyllithium 
• 927-77-5 n-propylmagnesium bromide 
• 614-47-1 1,3-diphenyl-propen-3-one 
• 80460-05-5 4-Nitro-1,3-diphenyl-1-hexanone 

Relevant articles and documents

Rh-catalyzed 1,4-addition of triallyl(aryl)silanes to α,β-unsaturated carbonyl compounds

Rh-catalyzed 1,4-addition of triallyl(aryl)silane to α,β-unsaturated carbonyl compounds was developed. Triallyl(aryl)silanes were used as air- and moisture-stable silicon nucleophiles. Allylsilanes were converted to silanols in situ and underwent transmetalation. This method can accept a wide range of functionalized triallyl(aryl)silane and α,β-unsaturated carbonyl compounds.

Palladium-catalyzed conjugate addition of organosiloxanes to α,β-unsaturated carbonyl compounds and nitroalkenes

The addition of aryltrialkoxysilanes to α,β-unsaturated carbonyl compounds (ketones, aldehydes) and nitroalkenes in the presence of SbCl3, TBAF, AcOH, and a catalytic amount of Pd(OAc)2, in CH3CN at 60 °C, provides the corresponding conjugate addition products in moderate to good yields. The addition of equimolar amounts of SbCl3 and TBAF is necessary for this reaction to proceed smoothly. The arylpalladium complex, which is generated by the transmetalation from a putative hypercoordinate silicon compound, is considered to be the catalytically active species.

New Synthetic Methods. Conjugate Addition of Alkyl Groups to Electron Deficient Olefins with Nitroalkanes as Alkyl Anion Equivalents

The sequence of the Michael addition of nitroalkanes and denitration from the adduct provides a new and general method for conjugate addition of primary and secondary alkyl groups to electron deficient olefins such as α,β-unsaturated aldehydes, ketones, esters, nitriles, sulfoxides, and sulfones.