42925-43-9

Basic information

• Product Name: 2-Hexen-1-one, 1-phenyl-
• CAS NO: 42925-43-9
• Molecular Formula: C12H14O
• Molecular Weight: 174.243
• Mol File: 42925-43-9.mol
• Article Data: 20

Chemical Properties

• CAS DataBase Reference: 2-Hexen-1-one, 1-phenyl-(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Hexen-1-one, 1-phenyl-(42925-43-9)
• EPA Substance Registry System: 2-Hexen-1-one, 1-phenyl-(42925-43-9)

Safety Data

• Hazardous Substances Data: 42925-43-9(Hazardous Substances Data)

Upstream product

• 18802-95-4 hex-2-enoyl chloride 
• 71-43-2 benzene 
• 2648-61-5 2,2-dichloroacetophenone 
• 123-72-8 butyraldehyde 
• 20913-05-7 (Benzoylmethylene)triphenylphosphorane 
• 1817-51-2 1-phenyl-1-hexyn-3-ol 
• 98-85-1 1-Phenylethanol 
• 71-36-3 butan-1-ol 
• 57548-41-1 3-hydroxy-1-phenylhexan-1-one 
• 603-35-0 triphenylphosphine 
• 98-86-2 acetophenone 
• 6048-29-9 triphenylphenacylphosphonium bromide 
• 536-74-3 phenylacetylene 
• 134240-74-7 1-n-propyl-3-phenylprop-2-ynyl acetate 

Downstream Products

• 59824-89-4 2,4-diphenyl-6-propyl-6H-[1,3]thiazine 
• 1177445-22-5 (E)-1-phenyl-3-styrylhexan-1-one 
• 1177445-24-7 (E)-3-(4-methoxystyryl)-1-phenylhexan-1-one 
• 1177445-23-6 (E)-1-phenyl-3-(4-(trifluoromethyl)styryl)hexan-1-one 
• 1454-59-7 1,3-diphenyl-1-hexanone 
• 1402164-71-9 (S)-1,3-diphenylhexan-1-one 
• 945983-13-1 C₁₉H₂₀Cl₂O₂S 
• 688364-91-2 (1R,3R)-3-[(1S,4R)-2-oxobornane-10-sulfenyl]-1-phenyl-1-hexanol 
• 688364-84-3 (1R,3S)-3-[(1S,4R)-2-oxobornane-10-sulfenyl]-1-phenyl-1-hexanol 
• 182692-64-4 (2R,3S)-phenyl-(3-propyloxiran-2-yl)methanone 

Relevant articles and documents

Bi(OTf)3-Catalyzed Alkyl-Intercepted Meyer-Schuster Rearrangement of Propargylic Alcohols for the Synthesis of 1,2,3,5-Tetrasubstituted Pentane-1,5-diones

An alkyl intercepted Meyer-Schuster rearrangement reaction with α,β-unsaturated ketones as the electrophiles was first investigated, which provided a facile method to construct 2-methylene-pentane-1,5-diones. Then the in situ generated 2-methylene-pentane-1,5-diones underwent a Michael addition to give diverse 2-malononitrile methyl substituted pentane-1,5-diones in a one-pot fashion. This transformation was reliable on a gram scale. The high yield, convenient experimental operation, and 100% atom economy made it a valuable method for the construction of 1,2,3,5-tetrasubstituted pentane-1,5-dione derivatives.

Enantioselective Conjugate Azidation of α,β-Unsaturated Ketones under Bifunctional Organocatalysis by Direct Activation of TMSN3

An enantioselective organocatalytic conjugate azidation of α,β-unsaturated ketones is presented. A bifunctional organocatalyst activates TMSN3, triggering the nucleophilic addition of the azido group to enones in absence of external promoters and avoiding the direct use or the pre-formation of highly toxic and explosive hydrazoic acid. This protocol proceeds with excellent enantiocontrol under mild conditions. DFT calculations and mechanistic trials have been performed in order to demonstrate the direct activation performed by the bifunctional organocatalyst. (Figure presented.).

Kinetic Resolution of β-Hydroxy Carbonyl Compounds via Enantioselective Dehydration Using a Cation-Binding Catalyst: Facile Access to Enantiopure Chiral Aldols

A practical and highly enantioselective nonenzymatic kinetic resolution of racemic β-hydroxy carbonyl (aldol) compounds through enantioselective dehydration process was developed using a cation-binding Song's oligoethylene glycol (oligoEG) catalyst with p