16012-40-1

Basic information

• Product Name: Benzenamine, 4-chloro-N,N-bis(4-chlorophenyl)-
• CAS NO: 16012-40-1
• Molecular Formula: C18H12Cl3N
• Molecular Weight: 348.659
• Mol File: 16012-40-1.mol
• Article Data: 7

Chemical Properties

• CAS DataBase Reference: Benzenamine, 4-chloro-N,N-bis(4-chlorophenyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzenamine, 4-chloro-N,N-bis(4-chlorophenyl)-(16012-40-1)
• EPA Substance Registry System: Benzenamine, 4-chloro-N,N-bis(4-chlorophenyl)-(16012-40-1)

Safety Data

• Hazardous Substances Data: 16012-40-1(Hazardous Substances Data)

Upstream product

• 637-87-6 1-Chloro-4-iodobenzene 
• 106-47-8 4-chloro-aniline 
• 106-39-8 bromochlorobenzene 

Downstream Products

• 1134195-28-0 4,4',4''-trichloro-2,2',2''-trinitrotriphenylamine 

Relevant articles and documents

Dye-sensitized electron transfer from TiO2 to oxidized triphenylamines that follows first-order kinetics

Two sensitizers, [Ru(bpy)2(dcb)]2+ (RuC) and [Ru(bpy)2(dpb)]2+ (RuP), where bpy is 2,2′-bipyridine, dcb is 4,4′-dicarboxylic acid-2,2′-bipyridine and dpb is 4,4′-diphosphonic acid-2,2′-bipyridine, were anchored to mesoporous TiO2 thin films and utilized to sensitize the reaction of TiO2 electrons with oxidized triphenylamines, TiO2(e-) + TPA+ → TiO2 + TPA, to visible light in CH3CN electrolytes. A family of four symmetrically substituted triphenylamines (TPAs) with formal Eo(TPA+/0) reduction potentials that spanned a 0.5 eV range was investigated. Surprisingly, the reaction followed first-order kinetics for two TPAs that provided the largest thermodynamic driving force. Such first-order reactivity indicates a strong Coulombic interaction between TPA+ and TiO2 that enables the injected electron to tunnel back in one concerted step. The kinetics for the other TPA derivatives were non-exponential and were modelled with the Kohlrausch-William-Watts (KWW) function. A Perrin-like reaction sphere model is proposed to rationalize the kinetic data. The activation energies were the same for all of the TPAs, within experimental error. The average rate constants were found to increase with the thermodynamic driving force, consistent with electron transfer in the Marcus normal region.

Selective oxidation of an electronically unsymmetrical distyrylbenzene at either of two sites

A p-distyrylbenzene bearing electron-withdrawing groups on one terminal ring and electron-supplying groups on the other was synthesized and one ring was found to be significantly more electron rich than the other. Electrochemical oxidative cleavage was sh

Copper-catalyzed synthesis of triarylamines from aryl halides and arylamines

A simple and efficient methodology for the synthesis of triphenylamines has been demonstrated using copper catalyst with a ligand and tripotassium phosphate as the base. The effect of parameters such as catalyst precursors, ligands, bases and solvents were studied and a series of triphenylamines were obtained with moderate to excellent yields in DMF. This reaction displays great functional groups compatibility in the presence of a broad range of functional groups.