16882-08-9Relevant articles and documents
Solvent and substituent effects on the photochemistry of norbornadiene-diarylacetylene pauson-khand adducts
Ji, Yining,Verdaguer, Xavier,Riera, Antoni
, p. 3942 - 3948 (2011)
The photochemistry of Pauson-Khand cycloadducts of norbornadiene with a series of bis-aryl alkynes has been studied. Two types of photochemical transformation take place: photorearrangement to tricyclic ketones or photochemical 6π electrocyclization. High
Synthesis and Selective CO2 Capture Properties of a Series of Hexatopic Linker-Based Metal-Organic Frameworks
Nguyen, Phuong T. K.,Nguyen, Huong T. D.,Pham, Hung Q.,Kim, Jaheon,Cordova, Kyle E.,Furukawa, Hiroyasu
, p. 10065 - 10072 (2015)
Four crystalline, porous metal-organic frameworks (MOFs), based on a new hexatopic linker, 1′,2′,3′,4′,5′,6′-hexakis(4-carboxyphenyl)benzene (H6CPB), were synthesized and fully characterized. Interestingly, two members of this series exhibited
Structural studies on inclusion compounds and solvent sorption behavior of gradually elongated wheel-and-axle-type diol hosts featuring lateral benzo[b]thiophene units
Katzsch, Felix,Gruber, Tobias,Weber, Edwin
, p. 48 - 64 (2016)
Based on the wheel-and-axle design strategy, a series of six new clathrate hosts featuring two di(benzo[b]thien-2-yl)hydroxymethyl units attached to both ends of a central linear building element of varying length have been synthesized and their capability to form crystalline inclusion compounds with a fixed range of organic solvents are reported. X-ray crystal structures of relevant inclusion compounds have been determined and are comparatively discussed involving structural modification of the host molecules. Organic vapor sorption behavior of the host compounds coated as solid films on the quartz crystal of a QCM device has been studied. Significant differences in the affinities towards solvent vapors dependent both on structural and polarity properties of host and solvent are observed, indicating potential application as mass sensitive materials.
One-step Ethylene Purification from an Acetylene/Ethylene/Ethane Ternary Mixture by Cyclopentadiene Cobalt-Functionalized Metal–Organic Frameworks
Wang, Yutong,Hao, Chunlian,Fan, Weidong,Fu, Mingyue,Wang, Xiaokang,Wang, Zhikun,Zhu, Lei,Li, Yue,Lu, Xiaoqing,Dai, Fangna,Kang, Zixi,Wang, Rongming,Guo, Wenyue,Hu, Songqing,Sun, Daofeng
supporting information, p. 11350 - 11358 (2021/04/05)
The separation of ethylene (C2H4) from a mixture of ethane (C2H6), ethylene (C2H4), and acetylene (C2H2) at normal temperature and pressure is a significant challenge. The sieving effect of pores is powerless due to the similar molecular size and kinetic diameter of these molecules. We report a new modification method based on a stable ftw topological Zr-MOF platform (MOF-525). Introduction of a cyclopentadiene cobalt functional group led to new ftw-type MOFs materials (UPC-612 and UPC-613), which increase the host-guest interaction and achieve efficient ethylene purification from the mixture of hydrocarbon gases. The high performance of UPC-612 and UPC-613 for C2H2/C2H4/C2H6 separation has been verified by gas sorption isotherms, density functional theory (DFT), and experimentally determined breakthrough curves. This work provides a one-step separation of the ternary gas mixture and can further serve as a blueprint for the design and construction of function-oriented porous structures for such applications.
Robust Alkyne Metathesis Catalyzed by Air Stable d2Re(V) Alkylidyne Complexes
Cui, Mingxu,Bai, Wei,Sung, Herman H. Y.,Williams, Ian D.,Jia, Guochen
supporting information, p. 13339 - 13344 (2020/09/03)
We report in this communication the first example of catalytic alkyne metathesis reactions mediated by well-defined non-d0 alkylidyne complexes. The air-stable d2 Re(V) alkylidyne complex Re4, bearing two PO-chelating ligands and a labile pyridine ligand, could catalyze homometathesis of internal alkynes with a broad substrate scope, including alcohols, amines, and even carboxylic acids. The catalyst can tolerate heating, air, and moisture in both solid and solution states, and the catalytic metathesis reactions could proceed normally in wet solvents.