192935-78-7Relevant articles and documents
Cobalt-catalyzed regioselective syntheses of indeno[2,1-: C] pyridines from nitriles and diynes bearing propargyl fragments
Xu, Murong,Zheng, Zhong,Wang, Mengdan,Kong, Lingkai,Ao, Yujuan,Li, Yanzhong
supporting information, p. 8761 - 8768 (2018/11/30)
A highly efficient CoI2/o-phenanthroline catalyzed cycloaddition reaction of diynes bearing TBS protected propargylic alcohol fragments with nitriles has been developed. This methodology offers regioselective access, with good functional group tolerance, to various indeno[2,1-c]pyridine derivatives in moderate to excellent yields. It was found that o-phenanthroline as a bidentate nitrogen ligand showed high efficacy in this cycloaddition reaction.
Gold-catalyzed cascade friedel-crafts/furan-yne cyclization/heteroenyne metathesis for the highly efficient construction of phenanthrene derivatives
Chen, Yifeng,Li, Guijie,Liu, Yuanhong
supporting information; experimental part, p. 392 - 400 (2011/04/22)
A rapid access to highly substituted phenanthrenyl ketones through gold-catalyzed cyclization of 1,6-diyn-4-en-3-ols with furans has been developed. Gold catalysts are effective to catalyze three cascade processes involving Friedel-Crafts/furan-yne cyclization/heteroenyne metathesis through C-O bond and alkyne activation. This method offers several advantages such as high selectivities and easily accessible starting materials.