6976-69-8Relevant articles and documents
Method for synthesizing aromatic acid ester
-
Paragraph 0029; 0030; 0042, (2017/09/05)
The invention relates to a method for synthesizing aromatic acid ester. Corresponding aromatic acid ester is synthesized from aromatic acid and lower carbon alcohol used as raw materials with a catalytic esterification means through an esterification reaction performed by efficiently catalyzing aromatic acid and lower carbon alcohol with a solid acid catalyst with the surface modified with a sulfonic acid group and immobilized with an imidazole acid ionic liquid at a certain temperature. The catalytic reaction operation is simple, the selectivity of the aromatic ester product can reach 99% or above when aromatic acid is completely converted, and the catalyst has good hydrothermal stability and reusability.
Efficient Baeyer-Villiger electro-oxidation of ketones with molecular oxygen using an activated carbon fiber electrode in ionic liquid [bmim][OTf]
Hu, Yu Lin,Xie, Yi Bi,Li, De Jiang
, p. 297 - 306 (2016/08/05)
A new and efficient method for the synthesis of lactones and esters involving the application of an molecular oxygen-based electro-catalytic oxidation system and ionic liquid [bmim][OTf] as electrolyte has been developed. The reaction between various ketones with molecular oxygen proceeds in a three-electrode cell under constant current conditions in [bmim][OTf] at room temperature to give the corresponding esters and lactones in good to excellent isolated yield. Additionally, the possible mechanism of Baeyer-Villiger oxidation of ketones in the electro-catalytic system is proposed.
Efficient and simple approaches towards direct oxidative esterification of alcohols
Ray, Ritwika,Jana, Rahul Dev,Bhadra, Mayukh,Maiti, Debabrata,Lahiri, Goutam Kumar
supporting information, p. 15618 - 15624 (2016/02/18)
The present article describes novel oxidative protocols for direct esterification of alcohols. The protocols involve successful demonstrations of both "cross" and "self" esterification of a wide variety of alcohols. The cross-esterification proceeds under a simple transition-metal-free condition, containing catalytic amounts of TEMPO (2,2,6,6-tetramethyl-1-piperidinyloxy)/TBAB (tetra-n-butylammonium bromide) in combination with oxone (potassium peroxo monosulfate) as the oxidant, whereas the self-esterification is achieved through simple induction of Fe(OAc)2/dipic (dipic=2,6-pyridinedicarboxylic acid) as the active catalyst under an identical oxidizing environment. One-pot oxidative esterification: A wide variety of alcohols undergo transition-metal-free (in the presence of oxone/2,2,6,6-tetramethyl-1-piperidinyloxy (TEMPO)/tetra-n-butylammonium bromide (TBAB)) selective "cross" esterification in moderate to excellent yields (see Figure). The "self" esterification process has however been achieved in the presence of Fe(OAc)2/2,6-pyridinedicarboxylic acid (dipic) as the active catalytic species under a similar oxidizing environment.