2074-29-5

Basic information

• Product Name: gibberellin A₄ methyl ester
• CAS NO: 2074-29-5
• Molecular Weight: 346.423
• Mol File: 2074-29-5.mol
• Article Data: 7

Chemical Properties

• CAS DataBase Reference: gibberellin A₄ methyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: gibberellin A₄ methyl ester(2074-29-5)
• EPA Substance Registry System: gibberellin A₄ methyl ester(2074-29-5)

Safety Data

• Hazardous Substances Data: 2074-29-5(Hazardous Substances Data)

Upstream product

• 75884-80-9 methyl 3-didehydrogibberellin A₇ 
• 75885-06-2 C₂₇H₃₀O₅S 
• 198990-73-7 ent-3α-acetoxy-10β-hydroxy-13-iodo-20-norgibberell-16-ene-7,19-dioic acid 7-methyl ester 19,10-lactone 
• 55732-63-3 ent-3α-acetoxy-13-hydroxy-gibberella-1,16-dien-7-oic acid 7-mehyl ester 19,10-lactone 
• 151670-90-5 ent-3α-acetoxy-10β-hydroxy-13-methylsulfonyloxy-20-norgibberell-16-ene-7,19-dioic acid 7-methyl ester 19,10-lactone 
• 53399-75-0 2β-acetoxy-4a,7-dihydroxy-1β-methyl-8-methylene-4aα,7β-gibbane-1α,10β-dicarboxylic acid-1=>4a lactone-10-methyl ester 
• 510-50-9 gibberellic acid methyl ester 
• 2074-29-5 gibberellin A₄ methyl ester 
• 186581-53-3 diazomethane 
• 468-44-0 Gibberellin A₄ 
• 75884-80-9 ent-10β-hydroxy-3-oxo-20-norgibberell-1,16-diene-7,19-dioic acid 7-methyl ester 19,10-lactone 

Downstream Products

• 2074-29-5 3-epi-gibberellin A₄ methyl ester 
• 2112-08-5 gibberellin A₉ 7-methyl ester 
• 2112-08-5 gibberellin A₉ methyl ester 
• 427-77-0 Gibberellin-A⁽⁹⁾ 
• 19124-90-4 gibberellin A₄ methyl ester 
• 75885-06-2 C₂₇H₃₀O₅S 

Relevant articles and documents

A New Method for the Deoxygenation of Tertiary and Secondary Alcohols

The derivatisation of alcohols as their methyl oxalyl esters is shown to be a convenient and selective method for deoxygenation by stannyl radicals.

Isolation and stereocontrolled synthesis of a 17-hydroxy-16β, 17-dihydrogibberellin, GA82

A 17-hydroxy-16β, 17-dihydrogibberellin, GA829, was first isolated from a fungus, Phaeosphaeria sp. L487, and was synthesized from naturally abundant GA41 in a highly stereocontrolled manner whose essential step was inversion of C(16) configuration of readily accessible 16β-formyl intermediate 5 to more stable 16α-epimer 6 by base treatment.

N.m.r. Assignements of Ring A Hydrogens in Gibberellin A4 Methyl Esters and some Derivatives

Full assignements of the 1H n.m.r. chemical shifts of the ring A protons in gibberellin A4, 3-epi-gibberellin A4 and 3-oxogibberellin A4 methyl esters have been made on the basis of 1H and 2H n.m.r. data of -, -, and -labelled derivatives.These assignements have been used to determine the stereochemistry of the deuterium atoms in gibberellin A4 methyl ester, prepared via catalytic deuteriogenation of gibberellin A7 16,17-epoxide methyl ester.