3386-35-4Relevant articles and documents
Cation and leaving group effects in isosorbide alkylation under microwave in phase transfer catalysis
Chatti, Saber,Bortolussi, Michel,Loupy, André
, p. 4365 - 4370 (2001)
We have studied cation, salt, leaving group effects and influence of catalyst under phase transfer catalysis conditions using concomitant microwave irradiation during di-n-octylation of isosorbide. A small amount of solvent was necessary to control temper
Combinatorial discovery of thermoresponsive cycloammonium ionic liquids
Chu, Yen-Ho,Hwang, Chun-Chieh,Chen, Chien-Yuan,Tseng, Min-Jen
supporting information, p. 11855 - 11858 (2020/10/13)
This work demonstrated, for the first time, the combinatorial discovery and rational identification of small-molecule cycloammonium-based thermoresponsive ionic liquids that exhibit LCST phase transition and carry attractiveTcvalues in water.
Cobalt-Catalyzed Silylcarbonylation of Unactivated Secondary Alkyl Tosylates at Low Pressure
Roque Pena, Joan E.,Alexanian, Erik J.
supporting information, p. 4413 - 4415 (2017/09/11)
A catalytic preparation of silyl enol ethers from unactivated secondary alkyl tosylates is reported. An inexpensive cobalt catalyst is used under mild conditions with low pressures of carbon monoxide. Nucleophilic, anionic cobalt carbonyls facilitate the catalytic activation of a range of alkyl tosylates. The silylcarbonylation offers a practical approach to synthetically valuable silyl enol ethers from simple starting materials.