38612-13-4

Basic information

• Product Name: 4-bromobenzyl benzoate
• Synonyms: 4-bromobenzyl benzoate
• CAS NO: 38612-13-4
• Molecular Weight: 291.144
• Mol File: 38612-13-4.mol
• Article Data: 9

Chemical Properties

• CAS DataBase Reference: 4-bromobenzyl benzoate(CAS DataBase Reference)
• NIST Chemistry Reference: 4-bromobenzyl benzoate(38612-13-4)
• EPA Substance Registry System: 4-bromobenzyl benzoate(38612-13-4)

Safety Data

• Hazardous Substances Data: 38612-13-4(Hazardous Substances Data)

Upstream product

• 532-32-1 sodium benzoate 
• 589-15-1 1-bromomethyl-4-bromobenzene 
• 873-75-6 4-bromobenzenemethanol 
• 98-88-4 benzoyl chloride 
• 1005-01-2 benzoic-acid-d1 
• 6274-57-3 (4-bromobenzyl)dimethylamine 
• 762-42-5 dimethyl acetylenedicarboxylate 
• 65-85-0 benzoic acid 
• 106-38-7 para-bromotoluene 
• 100-51-6 benzyl alcohol 
• 120-46-7 1,3-diphenylpropanedione 
• 100-53-8 phenylmethanethiol 
• 57477-93-7 hydrazone of p-bromobenzaldehyde 
• 85909-02-0 N-benzyl-N-(tert-butoxycarbonyl)-benzamide 

Downstream Products

• 134838-29-2 4-cyanobenzyl benzoate 
• 1215298-35-3 methyl 2-ethoxy-1-({2′-[1-(phenylmethyl)-1H-tetrazol-5-yl][1,1′-biphenyl]-4-yl}methyl)-1H-benzimidazole-7-carboxylate 
• 1307853-85-5 1-{[(cyclohexyloxy)carbonyl]oxy}ethyl 1-({4-[2-(1-benzyl-1H-1,2,3,4-tetrazol-5-yl)phenyl]phenyl}methyl)-2-ethoxy-1H-1,3-benzodiazole-7-carboxylate 
• 145040-37-5 candesartan cilexetil 
• 144689-23-6 ethyl 4-(1-hydroxy-1-methylethyl)-2-propyl-1-{[2′-(1H-tetrazol-5-yl)-1,1′-biphenyl-4-yl]methyl}-1H-imidazole-5-carboxylate 
• 144690-33-5 ethyl 4-(2-hydroxypropan-2-yl)-2-propyl-1-({2'-[1-(triphenylmethyl)-1H-1,2,3,4-tetrazol-5-yl]-[1,1'-biphenyl]-4-yl}methyl)-1H-imidazole-5-carboxylate 
• 936114-12-4 potassium 4-(1-hydroxy-1-methylethyl)-2-propyl-1-[[2'-[1-(triphenylmethyl)-1H-tetrazol-5-yl]biphenyl-4-yl]methyl]imidazole-5-carboxylate 
• 144690-92-6 trityl olmesartan medoxomil 
• 144689-63-4 olmesartan medoxomil 

Relevant articles and documents

Catalytic conversion of ketones to esters: Via C(O)-C bond cleavage under transition-metal free conditions

The catalytic conversion of ketones to esters via C(O)-C bond cleavage under transition-metal free conditions is reported. This catalytic process proceeds under solvent-free conditions and offers an easy operational procedure, broad substrate scope with excellent selectivity, and reaction scalability. This journal is

Bu 4 NI-Catalyzed C-C Bond Cleavage and Oxidative Esteri??cation of Allyl Alcohols with Toluene Derivatives

A novel oxidative esterification of 1-arylprop-2-en-1-ols with toluene derivatives catalyzed by tetrabutylammonium iodide (TBAI) is reported. The optimization of the reaction conditions illustrates that each of experiment parameters including the catalyst, solvent, and oxidant is significant for present oxidative functionalization. This metal-free protocol has a broad substrate scope including the halogen groups for further functionalization and enriches the reactivity profile of allyl alcohol and toluene derivatives. In addition, this protocol represents a new transformation of allyl alcohol involving C-C bond cleavage and C-O bond forming.

Copper-catalyzed cross-coupling of thiols, alcohols, and oxygen for the synthesis of esters

Copper-catalyzed, one-pot, three-component coupling reactions using thiols, alcohols, and oxygen to form a variety of esters in good yields were studied. In the presence of easily oxidized benzylic and allylic alcohols, thiols were selectively oxidized to form thionoesters, which underwent facile S/O exchange to afford esters. Thiols may be used as an alternative benzoyl source under mild aerobic conditions.