40358-51-8Relevant articles and documents
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Sherwood,Short,Stansfield
, p. 1832,1834 (1932)
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Arylalkene synthesis via decarboxylative cross-coupling of alkenyl halides
Tang, Jie,Goossen, Lukas J.
supporting information, p. 2664 - 2667 (2014/06/09)
A bimetallic catalyst system generated from readily available palladium(II) and copper(I) salts, 1,10-phenanthroline and tri-1-naphthylphosphine was found to efficiently mediate the decarboxylative cross-coupling of alkenyl bromides and chlorides with aromatic carboxylates. It allows the regiospecific synthesis of a broad range of aryl- and heteroarylalkenes in high yields.
FeCl3/Nal-catalyzed allylic C-H oxidation of arylalkenes with a catalytic amount of disulfide under air
Huang, Deshun,Wang, Haining,Xue, Fazhen,Shi, Yian
body text, p. 7269 - 7274 (2011/10/09)
This paper describes a FeCl3/NaI-catalyzed formal allylic C-H oxidation of arylalkenes using a catalytic amount of disulfide with BnOH and 4-nitroaniline as nucleophiles and air as oxidant to form the corresponding allyl ethers and amines. A possible reaction mechanism has been proposed.