42134-74-7

Basic information

• Product Name: Benzene, 1,1'-(1E)-1,2-ethenediylbis[4-(trifluoromethyl)-
• CAS NO: 42134-74-7
• Molecular Formula: C16H10F6
• Molecular Weight: 316.246
• Mol File: 42134-74-7.mol
• Article Data: 22

Chemical Properties

• CAS DataBase Reference: Benzene, 1,1'-(1E)-1,2-ethenediylbis[4-(trifluoromethyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1,1'-(1E)-1,2-ethenediylbis[4-(trifluoromethyl)-(42134-74-7)
• EPA Substance Registry System: Benzene, 1,1'-(1E)-1,2-ethenediylbis[4-(trifluoromethyl)-(42134-74-7)

Safety Data

• Hazardous Substances Data: 42134-74-7(Hazardous Substances Data)

Upstream product

• 455-19-6 4-Trifluoromethylbenzaldehyde 
• 38733-98-1 4-(trifluoromethyl)benzyltriphenylphosphonium bromide 
• 402-50-6 1-trifluoromethyl-4-vinyl-benzene 
• 99578-68-4 diethyl (4-(trifluoromethyl)benzyl)phosphonate 
• 1873-88-7 1,1,1,3,5,5,5-heptamethyltrisiloxan 
• 119757-51-6 1,2-bis(4-(trifluoromethyl)phenyl)ethyne 
• 2338-75-2 4-(Trifluoromethyl)phenylacetonitrile 
• 939-99-1 4-trifluoromethylbenzyl chloride 
• 98-56-6 4-chlorobenzotrifluoride 
• 32857-62-8 4-Trifluoromethylphenylacetic acid 
• 349-95-1 4-(trifluoromethyl)benzylic alcohol 
• 402-49-3 4-bromomethyltrifluoromethylbenzene 
• 603-35-0 triphenylphosphine 
• 42134-68-9 E-2-(4-trifluoromethylphenyl)-3-(4-trifluoromethylphenyl)acrylic acid 

Downstream Products

• 135733-72-1 C₁₆H₁₀Br₂F₆ 
• 42134-71-4 1,2-bis(4-(trifluoromethyl)phenyl)ethane 
• 213776-03-5 (R,R)-(+)-1,2-bis(4-trifluoromethylphenyl)ethane-1,2-diol 
• 1182735-05-2 [(4S,5S)-4,5-dihydro-4,5-bis[4-(trifluoromethyl)phenyl]isoxazol-3-yl][(3aS,6R,7aR)-tetrahydro-8,8-dimethyl-2,2-dioxido-3H-3a,6-methano-2,1-benzisothiazol-1,(4H)-yl]methanone 
• 327628-47-7 cis-2,3-bis(4-(trifluoromethyl)phenyl)oxirane 

Relevant articles and documents

Efficient preparation method of symmetric diarylethene compound

The invention belongs to the technical field of fine chemicals and related chemistry, and provides an efficient preparation method of a symmetric diarylethene compound. The method comprises the following steps: with halomethyl-containing aromatic hydrocarbon and derivatives thereof as raw materials, conducting reacting at 100 DEG C for 12 hours in the presence of a catalyst, alkali, additives andan anhydrous organic solvent so as to obtain the corresponding diarylethene compound with symmetry. The method has the beneficial effects that no transition metal reaction exists, reaction conditionsare mild, operation is simple and convenient, the possibility of industrialization is realized, and the diarylethene compound is obtained at high yield; and the diarylethene compound synthesized by using the method can be further functionalized to obtain various compounds, and is applied to development and research of natural products, functional materials and fine chemicals.

AIR-STABLE NI(0)-OLEFIN COMPLEXES AND THEIR USE AS CATALYSTS OR PRECATALYSTS

The present invention relates to air stable, binary Ni(0)-olefin complexes and their use in organic synthesis.

Ni(4?Tbustb)3: A robust 16-electron Ni(0) olefin complex for catalysis

Sixteen-electron Ni(0) complexes bearing trans-stilbene derivative ligands have been shown to display a high degree of stability toward oxidation in the solid state. A structural analysis of a unique family of tris Ni(0) stilbene complexes revealed a remarkable effect of the steric hindrance of the substituents at the para position of the stilbene unit to temperature, oxidation, and degradation in solution. From these analyses, Ni(4?tBustb)3 arose as a long-term air-, bench-. and temperature-stable Ni(0) complex. Importantly, Ni(4?tBustb)3 presents faster kinetic profiles and a broader scope as a Ni(0) source, thus outperforming the previously described Ni(4?CF3stb)3 in a variety of relevant Ni-catalyzed transformations.