43180-39-8

Basic information

• Product Name: N,N-dimethyl-1-phenylsulfanyl-methanamine
• Synonyms: N,N-dimethyl-1-phenylsulfanyl-methanamine;Dimethyl(phenylthiomethyl)amine
• CAS NO: 43180-39-8
• Molecular Formula: C₉H₁₃NS
• Molecular Weight: 167.2712
• Mol File: 43180-39-8.mol
• Article Data: 4

Chemical Properties

• Boiling Point: 221.4°Cat760mmHg
• Flash Point: 87.7°C
• Appearance: /
• Density: 1.04g/cm³
• Vapor Pressure: 0.108mmHg at 25°C
• Refractive Index: 1.57
• CAS DataBase Reference: N,N-dimethyl-1-phenylsulfanyl-methanamine(CAS DataBase Reference)
• NIST Chemistry Reference: N,N-dimethyl-1-phenylsulfanyl-methanamine(43180-39-8)
• EPA Substance Registry System: N,N-dimethyl-1-phenylsulfanyl-methanamine(43180-39-8)

Safety Data

• Hazardous Substances Data: 43180-39-8(Hazardous Substances Data)

Usage

Description

N,N-dimethyl-1-phenylsulfanyl-methanamine, also known as DMTS, is an organic compound that belongs to the class of amine chemicals. It has a molecular formula of C9H13NS and a molecular weight of 167.27 g/mol. DMTS is characterized by its strong and unpleasant odor and is considered toxic and harmful if ingested, inhaled, or brought into contact with the skin.

Uses

Used in Pharmaceutical Industry:
N,N-dimethyl-1-phenylsulfanyl-methanamine is used as a building block in the synthesis of pharmaceuticals for its versatile chemical properties, contributing to the development of various medicinal compounds.
Used in Agrochemical Industry:
N,N-dimethyl-1-phenylsulfanyl-methanamine serves as a key component in the production of agrochemicals, aiding in the creation of effective pesticides and other agricultural products.
Used in Dye Production:
N,N-dimethyl-1-phenylsulfanyl-methanamine is utilized as a chemical intermediate in the manufacturing of dyes, playing a crucial role in the coloration processes of various materials.
Used in Polymer Production:
N,N-dimethyl-1-phenylsulfanyl-methanamine contributes to the synthesis of polymers, enhancing their properties and expanding their applications in different industries.
Used in Other Industrial Chemicals:
N,N-dimethyl-1-phenylsulfanyl-methanamine is employed as an intermediate in the production of a wide range of industrial chemicals, showcasing its versatility and importance in chemical synthesis.
Safety Precautions:
When handling N,N-dimethyl-1-phenylsulfanyl-methanamine, it is essential to observe safety precautions such as wearing adequate protective gear to prevent ingestion, inhalation, or skin contact, due to its toxic and harmful nature.

InChI:InChI=1/C9H13NS/c1-10(2)8-11-9-6-4-3-5-7-9/h3-7H,8H2,1-2H3

Upstream product

• 108-98-5 thiophenol 
• 124-40-3 dimethyl amine 
• 33797-51-2 eschenmoser's salt 
• 50-00-0 formaldehyd 
• 51-80-9 bis-(dimethylamino)methane 
• 1353053-97-0 triethylsiloxymethyl-N,N-dimethylamine 

Downstream Products

• 7154-02-1 benzyl-dimethyl-(phenylsulfanyl-methyl)-ammonium; chloride 
• 6631-73-8 phenylthiomethyltrimethylammonium iodide 
• 39087-27-9 (3,7-dimethyl-octa-2,6-dienyl)-dimethyl-phenylsulfanylmethyl-ammonium; chloride 
• 62142-32-9 (2-Cyclohexylidene-ethyl)-dimethyl-phenylsulfanylmethyl-ammonium; bromide 
• 54926-32-8 1-(Diphenylmethylsilyl)-trimethylamin 
• 53174-43-9 Dimethylaminomethyltriphenylsilan 
• 39087-24-6 (4-Methoxy-benzyl)-dimethyl-phenylsulfanylmethyl-ammonium; chloride 
• 39087-25-7 Dimethyl-naphthalen-1-ylmethyl-phenylsulfanylmethyl-ammonium; chloride 
• 39087-26-8 dimethyl-(3-methyl-but-2-enyl)-phenylsulfanylmethyl-ammonium; chloride 
• 72443-64-2 N,N-Dimethyl-3-bromo-2-methylbenzylamine 
• 91551-17-6 [(2,7-dimethoxy-8-methyl-9,10-dihydro-3-phenanthryl)methyl]dimethyl[(phenylthio)methyl]ammonium bromide 
• 97860-97-4 dimethyl[(3-methoxy-9,10-dihydro-2-phenanthryl)methyl][(phenylthio)methyl]ammonium bromide 
• 97860-91-8 dimethyl[(2-methoxy-9,10-dihydro-3-phenanthryl)methyl][(phenylthio)methyl]ammonium bromide 

Relevant articles and documents

Triethylsiloxymethyl-N,N-dimethylamine, Et3SiOCH2NMe2: A Dimethylaminomethylation (Mannich) Reagent for O–H, S–H, P–H and Aromatic C–H Systems

Triethylsiloxymethylamine, Et3SiOCH2NMe2, readily synthesized in high yield by the hydrosilylation reaction between Et3SiH and DMF, is an excellent (N,N-dimethylamino)methyl transfer agent to a representative range of aliphatic alcohols, thiols, and Ph2PH (E–H) materials. The reactions are almost instantaneous at room temperature in inert solvents and require no activating agents to produce E–CH2NMe2 products in high yields and illustrate the title compound as an excellent addition to the family of organic reagents. For aromatic alcohols, electrophilic substitution of the aromatic ring occurs in high yield. Crystal structures of new materials such as the cholestero–CH2NMe2 derivative, 2–4-[bis(N,N-dimethylamino)methyl]-1-naphthol, and the phosphine oxide derived from Ph2PCH2NMe2 are reported.

Synthesis and novel reactivity of halomethyldimethylsulfonium salts

Iodomethyl-, chloromethyl-, and fluoromethyldimethylsulfonium salts, 4b-d, have been synthesized and are observed to be highly reactive molecules that exhibit extraordinary diversity with respect to the nature of their reactivity, undergoing facile direct substitution (SN2) reactions, but also being highly susceptible to electron-transfer reactions. Cyclic voltametry experiments indicated that the iodomethyldimethylsulfonium compound, 4b, is a potent electron acceptor, even surpassing the reactivity of perfluoro-n-alkyl iodides in that capacity. The iodo- and chloromethyldimethylsulfonium salts, 4b,c, as well as the analogous iodomethyltrimethylammonium salt, 3a, are shown to be reactive SET acceptors.