4923-85-7

Basic information

• Product Name: tert-butyl(phenyl)phosphinic chloride
• Synonyms: (1,1-DIMETHYLETHYL)PHENYLPHOSPHINIC CHLORIDE
• CAS NO: 4923-85-7
• Molecular Formula: C₁₀H₁₄ClOP
• Molecular Weight: 216.6443
• Mol File: 4923-85-7.mol
• Article Data: 8

Chemical Properties

• Boiling Point: 330.8°C at 760 mmHg
• Flash Point: 153.9°C
• Density: 1.11g/cm³
• Vapor Pressure: 0.000312mmHg at 25°C
• Refractive Index: 1.498
• CAS DataBase Reference: tert-butyl(phenyl)phosphinic chloride(CAS DataBase Reference)
• NIST Chemistry Reference: tert-butyl(phenyl)phosphinic chloride(4923-85-7)
• EPA Substance Registry System: tert-butyl(phenyl)phosphinic chloride(4923-85-7)

Safety Data

• Hazardous Substances Data: 4923-85-7(Hazardous Substances Data)

Upstream product

• 507-20-0 tertiary butyl chloride 
• 644-97-3 Dichlorophenylphosphine 
• 62485-00-1 isobutyl phosphorodichloridate 
• 71-43-2 benzene 
• 115-11-7 isobutene 
• 113502-18-4 P-(1,1-dimethylethyl)-P-phenylphosphinoselenoic acid Se-methyl ester 
• 76380-86-4 S-methyl tert-butylphenylphosphinothiolate 
• 29949-69-7 tert-butylchlorophenylphosphane 
• 51584-29-3 S-methyl tert-(butylphenylphosphino)thiolate 
• 51584-29-3 S-methyl tert-(butylphenylphosphino)thiolate 
• 6002-45-5 (+/-)-tert-butyl(phenyl)phosphinothioic O-acid 

Downstream Products

• 4923-86-8 t-butyl(phenyl)phosphinic acid 
• 84718-90-1 t-butyl(phenyl)phosphinic azide 
• 82220-41-5 tert-butylphenylphosphinic imidazolidide 
• 63283-74-9 R_(P)-t-Butyl-phenyl-phosphinsaeure-(-)-menthylester 
• 63246-15-1 S_(P)-t-Butyl-phenyl-phosphinsaeure-(-)-menthylester 
• 5994-87-6 diphenylphosphinamide 
• 85656-12-8 tert-butylphenylphosphinic acid methyl ester 
• 1262225-34-2 2-(t-butylphenylboranatophosphinyl)pent-2-eno-1,5-dicarboxylic acid dimethyl ester 

Relevant articles and documents

Reactivity of allyl anions of allylphosphine-boranes towards electrophiles

The reactivity of mesomeric carbanions derived from allylphosphine-boranes varies as a function of electrophile. Small sp3-electrophiles react predominantly at the α carbon atom whereas bulky sp3- electrophiles and carbonyl compounds react mainly at the γ carbon. In the case of electron-deficient aldehydes reduction of carbonyl group and formation of the corresponding alcohols is observed. This is attributed to the weakly reducing properties of carbanions derived from allylphosphine-boranes, whose mesomeric form resembles the structure of a modified borohydride. ARKAT-USA, Inc.

MECHANISM OF THE CHLOROLYSIS REACTION OF P-S BOND IN PHOSPHORUS THIOLOESTERS. THE EFFECT OF THE SUBSTITUENT AT SULFUR ATOM ON THE STEREOCHEMISTRY

The effect of the substituent at sulfur atom on the stereochemistry of the chlorolysis reaction of P-S bond in phosphorus thioloesters was studied.It was found that the presence of the substituents lowering electron density at this atom reduces the reacti

SILYLPEROXIDES AS SELECTIVE OXYGENATION REAGENTS IN PHOSPHORUS CHEMISRTY

Bis(trimethylsilyl)peroxide (BSPO) can be used for chemo- and stereoselective generation of P=O group by oxygenation of P(III) centre and transformation of P=S and P=Se groups.