55784-90-2

Basic information

• Product Name: (±)-Oxylubimin
• Synonyms: (±)-Oxylubimin;(2R,5S)-8β,9α-Dihydroxy-10β-methyl-2α-(1-methylvinyl)spiro[4.5]decane-6β-carbaldehyde
• CAS NO: 55784-90-2
• Molecular Formula: C15H24O3
• Molecular Weight: 252.34926
• Mol File: 55784-90-2.mol
• Article Data: 6

Chemical Properties

• Appearance: /
• CAS DataBase Reference: (±)-Oxylubimin(CAS DataBase Reference)
• NIST Chemistry Reference: (±)-Oxylubimin(55784-90-2)
• EPA Substance Registry System: (±)-Oxylubimin(55784-90-2)

Safety Data

• Hazardous Substances Data: 55784-90-2(Hazardous Substances Data)

Upstream product

• 55784-90-2 epioxylubimin 
• 101415-98-9 (2RS,5RS,8SR,9SR,10RS)-9-methoxymethoxy-6,10-dimethyl-2-pivaloyloxyspiro<4.5>dec-6-en-8-ol 
• 129165-36-2 Methanesulfonic acid 2-((2R,5S,8R,9R,10S)-6-formyl-8,9-bis-methoxymethoxy-10-methyl-spiro[4.5]dec-6-en-2-yl)-propyl ester 
• 101416-00-6 Methanesulfonic acid (2S,5S,8R,9R,10S)-8,9-bis-methoxymethoxy-6,10-dimethyl-spiro[4.5]dec-6-en-2-yl ester 
• 101467-36-1 (2RS,5RS,8SR,9SR,10RS)-8,9-bis(methoxymethoxy)-6,10-dimethyl-2-pivaloyloxyspiro<4.5>dec-6-ene 
• 101415-97-8 (2RS,5RS,9SR,10RS)-9-methoxymethoxy-6,10-dimethyl-2-pivaloyloxyspiro<4.5>dec-6-en-8-one 
• 101415-96-7 (2RS,5RS,9SR,10RS)-9-hydroxy-6,10-dimethyl-2-pivaloyloxyspiro<4.5>dec-6-en-8-one 
• 101415-99-0 (2RS,5RS,8SR,9SR,10RS)-8,9-bis(methoxymethoxy)-6,10-dimethyl-spiro<4.5>dec-6-en-2-ol 
• 55784-90-2 (+/-)-10-epioxylubimin 
• 101415-94-5 Methanesulfonic acid 2-((2R,5S,6S,7R,8R,10S)-10-formyl-7,8-dihydroxy-6-methyl-spiro[4.5]dec-2-yl)-propyl ester 
• 101416-08-4 (2RS,5SR,6SR,7RS,8RS,10SR)-10-ethylenedithiomethyl-2-isopropenyl-6-methylspiro<4.5>decane-7,8-diol 
• 101416-01-7 diethyl(2RS,5SR,8RS,9RS,10SR)-8,9-bis(methoxymethoxy)-6,10-dimethylspiro<4.5>dec-6-en-2-ylmalonate 
• 101416-04-0 (2RS,5SR,9RS,10SR)-6-hydroxymethyl-2-(2-mesyloxy-1-methylethyl)-8,9-bis(methoxymethoxy)-10-methylspiro<4.5>dec-6-ene 
• 101416-06-2 (2RS,5SR,6SR,8RS,9RS,10SR)-2-(2-mesyloxy-1-methylethyl)-7,8-bis(methoxymethoxy)-10-methylspiro<4.5>decane-6-carbaldehyde 

Downstream Products

• 61263-55-6 3-hydroxy-15-dihydrolubimin 
• 55784-90-2 10-epi-3-hydroxylubimin 
• 55784-90-2 oxylubimin 
• 61263-55-6 10-epi-3-hydroxy-15-dihydrolubimin 
• 55784-90-2 (+/-)-oxylubimin 
• 55784-90-2 (+/-)-10-epioxylubimin 
• 61263-55-6 Dihydrooxylubimin 

Relevant articles and documents

Synthetic studies on spirovetivane phytoalexins. V. A stereoselective total synthesis of (±)-oxylubimin

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A STEREOSELECTIVE TOTAL SYNTHESIS OF (+/-)-OXYLUBIMIN

(+/-)-Oxylubimin (1), the highest oxidized spirovetivane-type phytoalexin, was totally synthesized with high stereoselectivity using a novel method for α'-hydroxylation of α,β-unsaturated ketones.

Structure of Epilubimin, Epioxylubimin, and Isolubimin, Spirovetivane Stress Metabolites in Diseased Potato

The isolation and structure elucidation of the title spirovetivane sesquiterpenes, stress metabolites produced in diseased potato tubers, are described.