58155-85-4

Basic information

• Product Name: 6,8-dibromo-2-styryl-benzo[d][1,3]oxazin-4-one
• CAS NO: 58155-85-4
• Molecular Weight: 407.061
• Mol File: 58155-85-4.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 6,8-dibromo-2-styryl-benzo[d][1,3]oxazin-4-one(CAS DataBase Reference)
• NIST Chemistry Reference: 6,8-dibromo-2-styryl-benzo[d][1,3]oxazin-4-one(58155-85-4)
• EPA Substance Registry System: 6,8-dibromo-2-styryl-benzo[d][1,3]oxazin-4-one(58155-85-4)

Safety Data

• Hazardous Substances Data: 58155-85-4(Hazardous Substances Data)

Upstream product

• 102-92-1 cinnamoyl chloride 
• 609-85-8 2-amino-3,5-dibromobenzoic acid 
• 40889-42-7 6,8-dibromo-2-methyl-3,1-benzoxazin-4(H)-one 
• 100-52-7 benzaldehyde 

Downstream Products

• 78993-38-1 5,7-Dibromo-1-[(E)-(3-phenyl-acryloyl)]-1,3-dihydro-benzoimidazol-2-one 
• 78993-39-2 3,5-Dibromo-2-[5-((E)-styryl)-tetrazol-1-yl]-benzoic acid 
• 78993-33-6 (Z)-N-(2,4-Dibromo-6-hydrazinocarbonyl-phenyl)-3-phenyl-acrylamide 
• 78993-37-0 3-{3,5-Dibromo-2-[(Z)-(3-phenyl-acryloyl)amino]-phenyl}-3-oxo-propionic acid ethyl ester 
• 78993-32-5 N-Benzyl-3,5-dibromo-2-[(Z)-(3-phenyl-acryloyl)amino]-benzamide 

Relevant articles and documents

Reaction of 6,8-Dibromo-2-methyl-3,1-benzoxazin-4(H)-one with Some Nucleophilic Reagents : Synthesis of Quinazoline, Tetrazole and Benzimidazole Derivatives

6,8-Dibromo-2-methyl-3,1-benzoxazin-4(H)-one (1) reacts with primary amines, hydrazines, hydroxylamine and semicarbazide to give the ring opening products (2), (4), (9) and (12), respectively.Compounds (2) undergo cyclisation to 3-substituted 6,8-dibromo-2-methyl-4-quinazolones (3) when heated above their melting points.Action of selenium dioxide and N-bromosuccinimide on 3 has also been investigated.Compound (1) undergoes condensation with benzaldehyde to give (8) which reacts with benzylamine and hydrazine hydrate to give 9a and 9b, respectively.Compound (8) also reacts with hydrazoic acid to give a mixture of tetrazole (11) and benzimidazolone (12).