753490-95-8Relevant articles and documents
The disarming effect of the 4,6-acetal group on glycoside reactivity: Torsional or electronic?
Jensen, Henrik Helligso,Nordstrom, Lars Ulrik,Bols, Mikael
, p. 9205 - 9213 (2007/10/03)
An evaluation of whether the well-known deactivating effect of a 4,6-acetal protection group on glycosyl transfer is caused by torsional or an electronic effect from fixation of the 6-OH in the tg conformation was made. Two conformationally locked probe m