84519-66-4

Basic information

• Product Name: 4-phenyl-(Z)-2-pentene
• Synonyms: 4-phenyl-(Z)-2-pentene
• CAS NO: 84519-66-4
• Molecular Weight: 146.232
• Mol File: 84519-66-4.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 4-phenyl-(Z)-2-pentene(CAS DataBase Reference)
• NIST Chemistry Reference: 4-phenyl-(Z)-2-pentene(84519-66-4)
• EPA Substance Registry System: 4-phenyl-(Z)-2-pentene(84519-66-4)

Safety Data

• Hazardous Substances Data: 84519-66-4(Hazardous Substances Data)

Upstream product

• 926-58-9 (S)-(-)-Z-3-penten-2-ol 
• 100-56-1 phenylmercury(II) chloride 
• 24652-50-4 (Z)-pent-3-en-2-ol 
• 917-54-4 methyllithium 
• 84473-20-1 (R)-(+)-trans-α-methyl-γ-phenylallyl N-phenylcarbamate 

Downstream Products

• 32587-80-7 (S)-4-phenylpentan-2-one 

Relevant articles and documents

Stereochemistry of the Wacker Reaction: Modes of Addition of Hydroxide, Methoxide, and Phenyl at High and Low [Cl-]. A Study Using Chirality Transfer

-

Alkylation of Allylic Derivates. 4. On the Mechanism of Alkylation of Allylic N-Phenylcarbamates with Lithium Dialkylcuprates

Alkylation of allylic N-phenylcarbamates by deprotonation, complexation with CuI in THF, and addition of 1 equiv of RLi results in syn γ-alkylation in both cyclic and acyclic systems.This procedure gives higher stereo- and regiospecificity than when allylic N-phenylcarbamates are reacted with 3 equiv of etheral LiCuR2.A mechanism is presented which incorporates an intramolecular oxidative addition leading to a ?-allyl complex (3) which undergoes reductive elimination to give the syn γ-alkylation product.