929-25-9Relevant articles and documents
On the scope of the double Ugi multicomponent stapling to produce helical peptides
Ricardo, Manuel G.,Vázquéz-Mena, Yadiel,Iglesias-Morales, Yuleidys,Wessjohann, Ludger A.,Rivera, Daniel G.
, (2021)
The stabilization of helical structures by peptide stapling approaches is now a mature technology capable to provide a variety of biomedical applications. Recently, it was shown that multicomponent macrocyclization is not only an effective way to introduc
Reaction of Bidentate Isonitrile Ligands with Iron Carbonyls
Howell, James A. S.,Rowan, Anthony J.
, p. 297 - 301 (2007/10/02)
Reaction of the bidentate isonitriles CN(CH2)nNC ( n =2, 3, 4, or 6) with (cp = η-cyclopentadienyl) yields exclusively 2> derivatives which are fluxional in solution and exist in three isomeric forms (bridged-bridged, bridged-terminal, and terminal-terminal with respect to the bonding mode of the bidentate isonitrile).The proportion of the isomers containing terminally bound isonitrile increases with the length of the alkyl chain.The complexes may be protonated to yield 2>2 salts (n = 2 or 6) and may be cleaved with I2 to give and 2nNC>> (n = 2 or 6).Reaction ofCN(CH2)nNC (n = 2 or 6 with or yields exclusively 2nNC>>