Phosphorus, Sulfur and Silicon and the Related Elements p. 1464 - 1470 (2015)
Update date:2022-07-29
Topics:
Aghapour, Ghasem
Abbaszadeh, Zeinab
Direct and oxidative conversion of tetrahydropyranyl and silyl ethers to oximes is described using trichloroisocyanuric acid (TCCA) as a relatively stable and inexpensive oxidant surprisingly in a catalytic amount and hydroxylamine hydrochloride under solvent-free conditions. Oximes can be synthesized from these protected alcohols in the presence of some other functional groups with excellent chemoselectivity using the present tandem catalytic method.
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