10.1002/anie.202005066
Angewandte Chemie International Edition
Synthetic Methods
+
. e-rich & e-poor ArN2
G. J. Sherborne, A. G. Gevondian, I. Funes-
Ardoiz, A. Dahiya, C. Fricke, Franziska
Schoenebeck*
. mechanistic rationale
. [Ge]-selective
. I, Br, Cl, [Si], [B] tolerant
Page – Page
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Aryl germanes are readily available in
a
straightforward synthetic protocol from ary
l
halides via initial Grignard formation and subsequent reaction with Et3GeCl. This reagent is com
m
ercially available for
a
reasonable price of ~30 $/g. Trial ary germanes do not exhibit any toxicity
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