Oxirane,2-methyl-3-propyl-

Base Information

• Chemical Name: Oxirane,2-methyl-3-propyl-
• CAS No.: 1192-32-1
• Molecular Formula: C6H12 O
• Molecular Weight: 100.161
• Mol file: 1192-32-1.mol

Synonyms:Hexane,2,3-epoxy- (6CI,7CI,8CI); 2,3-Epoxyhexane; 2-Hexene oxide

Chemical Property of Oxirane,2-methyl-3-propyl-

Chemical Property:

• Boiling Point: 93.5 °C(Press: 748 Torr)
• PSA: 12.53000
• Density: 1.424 g/cm3
• LogP: 1.57380

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Oxirane,2-methyl-3-propyl-

There total 4 articles about Oxirane,2-methyl-3-propyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

hexane (110-54-3) → 2-ethyltetrahydrofuran (1003-30-1,123931-62-4) + 2-ethyl-4-methyloxetane (5410-21-9) + 2,5-dimethyltetrahydrofuran (1003-38-9) + 2,3-epoxyhexane (1192-32-1)

Guidance literature:

at 365 - 565 ℃; Produkt: 1,3-Epoxy-hexan;

DOI:10.1021/ie51394a030

Reference yield:

hexane (110-54-3) → oxirane (75-21-8,99932-75-9) + 2-ethyltetrahydrofuran (1003-30-1,123931-62-4) + 2-ethyl-4-methyloxetane (5410-21-9) + 2,5-dimethyltetrahydrofuran (1003-38-9) + 2-methyloxane (10141-72-7) + 2,3-diethyloxirane (4468-66-0,36611-93-5,36611-94-6,124718-82-7,135559-58-9,149951-15-5) + 1,2-Epoxyhexane (1436-34-6) + 2,3-epoxyhexane (1192-32-1) + 2-propyl-oxetane (4468-64-8) + methanol (67-56-1) + Ketene (463-51-4) + formaldehyd (50-00-0,30525-89-4,61233-19-0) + propene (187737-37-7,13987-01-4,15220-87-8,9003-07-0,676-63-1,25085-53-4) + methane (34557-54-5,27936-85-2) + ethane (74-84-0) + ethene (74-85-1) + 1,2-propanediene (463-49-0) + acetaldehyde (75-07-0,9002-91-9) + acetic acid (64-19-7,77671-22-8) + propionic acid (802294-64-0,79-09-4) + buta-1,3-diene (106-99-0,130983-70-9,29406-96-0,9003-17-2) + methyloxirane (75-56-9,16033-71-9) + prop-1-yne (74-99-7) + acetylene (74-86-2,25067-58-7)

Guidance literature:

With oxygen; at 376.84 ℃; for 0.000555556h; under 795.08 Torr; Temperature; Inert atmosphere;

DOI:10.1021/jp503772h

Reference yield:

cis-2-hexene (7688-21-3) → 2,3-epoxyhexane (1192-32-1) + n-hexan-3-ol (623-37-0) + n-hexan-2-ol (626-93-7) + n-hexan-2-one (591-78-6) + n-hexan-3-one (589-38-8)

Guidance literature:

With sodium tetrahydroborate; 5,10,15,20-tetra(4-methoxyphenyl) porphyrinato manganese chloride; oxygen; In ethanol; benzene; for 24h; Product distribution; Mechanism;

DOI:10.1007/BF00955780

upstream raw materials:

cis-2-hexene

hexane

2-hexene

Downstream raw materials:

acetaldehyde

acetic acid

butyraldehyde

2,3-dichloro-hexane

Refernces

• 1、 Wang, Zhandong,Herbinet, Olivier,Cheng, Zhanjun,Husson, Benoit,Fournet, Rene,Qi, Fei,Battin-Leclerc, Frederique. "Experimental investigation of the low temperature oxidation of the five isomers of hexane". . p. 5573 - 5594. Retrieved 2014/08/18.