2-Furancarboxylic acid, potassium salt

Base Information

• Chemical Name: 2-Furancarboxylic acid, potassium salt
• CAS No.: 20842-02-8
• Molecular Formula: C5H4O3.K
• Molecular Weight: 150.175
• Hs Code.: 2932190090
• Mol file: 20842-02-8.mol

Synonyms:potassium furancarboxylate;POTASSIUM FUROATE;potassium 2-furoate;Potassium furan-2-carboxylate;

Chemical Property of 2-Furancarboxylic acid, potassium salt

Chemical Property:

• PSA: 53.27000
• LogP: -0.35690

Purity/Quality:

≥99% ^*data from raw suppliers

Potassiumfuran-2-carboxylate 97% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 2-Furancarboxylic acid, potassium salt

There total 3 articles about 2-Furancarboxylic acid, potassium salt which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 94.0%

2-furanoic acid (88-14-2) → potassium furan-2-carboxylate (20842-02-8)

Guidance literature:

With potassium tert-butylate; In ethanol; at 20 ℃; Inert atmosphere;

DOI:10.1002/chem.200900892

Reference yield: 90.0%

2-furoic acid methyl ester (611-13-2) + potassium trimethylsilonate (10519-96-7) → potassium furan-2-carboxylate (20842-02-8)

Guidance literature:

In tetrahydrofuran;

Reference yield:

(2-furyl)methyl alcohol (98-00-0,25212-86-6,93793-62-5) → potassium furan-2-carboxylate (20842-02-8)

Guidance literature:

With chloro(η⁶-p-cymene)[2-(2,6-diisopropylphenyl)-5-(1,3-diisopropyl-2,4,6-trioxohexahydropyrimidin-5-yl-κC⁵)imidazo[1,5-a]pyridin-3-ylidene-κC³]ruthenium(II); potassium hydroxide; In dichloromethane; o-xylene; at 150 ℃; Schlenk technique;

DOI:10.1021/acs.organomet.1c00458

upstream raw materials:

2-furoic acid methyl ester

potassium trimethylsilonate

2-furanoic acid

(2-furyl)methyl alcohol

Downstream raw materials:

2-furoic acid methyl ester

furan-2-carboxylic acid phenyl ester

4-tolyl iodide

furan-2-carboxylic acid phenylamide

Refernces

• 1、 -. "Industrial preparation method of low-cost 2,5-furan dicarboxylic acid". Paragraph 0076; 0077-0081; 0083; 0089; 0092; 0095; 0098. . Retrieved 2018/10/19.
• 2、 Goossen, Lukas J.,Linder, Christophe,Rodriguez, Nuria,Lange, Paul P.. "Biaryl and aryl ketone synthesis via Pd-catalyzed decarboxylase coupling of carboxylate salts with aryl triflates". supporting information; experimental part. p. 9336 - 9349. Retrieved 2010/04/03.