3-(2,2-dimethylcyclopropyl)-3-chlorodiazirine

Base Information

• Chemical Name: 3-(2,2-dimethylcyclopropyl)-3-chlorodiazirine
• CAS No.: 151538-87-3
• Molecular Formula: C₆H₉ClN₂
• Molecular Weight: 144.604
• Mol file: 151538-87-3.mol

Synonyms:3-(2,2-dimethylcyclopropyl)-3-chlorodiazirine

Chemical Property of 3-(2,2-dimethylcyclopropyl)-3-chlorodiazirine

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

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Technology Process of 3-(2,2-dimethylcyclopropyl)-3-chlorodiazirine

There total 1 articles about 3-(2,2-dimethylcyclopropyl)-3-chlorodiazirine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

rac-2,2-dimethylcyclopropanecarbonitrile (5722-11-2,157728-61-5) → 3-(2,2-dimethylcyclopropyl)-3-chlorodiazirine (151538-87-3)

Guidance literature:

Multi-step reaction with 2 steps

1: 1.) HCl gas, 2.) ammonia / 1.) ethanol, 4 d, RT; 2.) ethanol, 0 deg C, 1 h

2: 46 percent / 1.) LiCl; 2.) NaOCl saturated with NaCl / dimethylsulfoxide; H₂O / 1.33 h / 0 °C

With hydrogenchloride; sodium hypochlorite; ammonia; lithium chloride; sodium chloride; In water; dimethyl sulfoxide;

DOI:10.1021/j100152a056

Reference yield: 59.2%

3-(2,2-dimethylcyclopropyl)-3-chlorodiazirine (151538-87-3) → chloroacetylene (593-63-5) + 1-Chloro-3,3-dimethyl-cyclobutene + 1-Chloro-4,4-dimethyl-cyclobutene + isobutene (115-11-7,15220-85-6)

Guidance literature:

In chloroform-d1; at 21 ℃; for 0.5h; Product distribution; Mechanism; Rate constant; Irradiation; also in pentane, sealed tube, 60 and 80 deg C;

DOI:10.1021/j100152a056

Reference yield:

2-methyl-but-2-ene (513-35-9) + 3-(2,2-dimethylcyclopropyl)-3-chlorodiazirine (151538-87-3) → chloroacetylene (593-63-5) + 1-Chloro-2,2,2',2'-tetramethyl-bicyclopropyl + 1-Chloro-3,3-dimethyl-cyclobutene + 1-Chloro-4,4-dimethyl-cyclobutene + isobutene (115-11-7,15220-85-6)

Guidance literature:

In pentane; at 25 ℃; Product distribution; Mechanism; Rate constant; Irradiation; varying quantities of Me₂C=CMe;

DOI:10.1021/j100152a056

upstream raw materials:

rac-2,2-dimethylcyclopropanecarbonitrile

Downstream raw materials:

chloroacetylene

isobutene

Refernces