MONOCHLOROACETYLENE

Base Information

• Chemical Name: MONOCHLOROACETYLENE
• CAS No.: 593-63-5
• Molecular Formula: C2H Cl
• Molecular Weight: 60.4829
• Mol file: 593-63-5.mol

Synonyms:Acetylene,chloro- (6CI,7CI,8CI); Chloroacetylene; Chloroethyne; Ethynyl chloride

Chemical Property of MONOCHLOROACETYLENE

Chemical Property:

• Vapor Pressure: 4860mmHg at 25°C
• Melting Point: -126°C
• Refractive Index: 1.4080 (estimate)
• Boiling Point: 11.58°C (estimate)
• PSA: 0.00000
• Density: 1.066g/cm³
• LogP: 0.81590

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Use Description: Monochloroacetylene, a highly reactive and potentially hazardous chemical compound, finds limited and specialized applications across different fields. In the field of chemistry, it can be used as a reagent for organic synthesis, particularly in the creation of complex organic molecules. However, its use is typically restricted to controlled laboratory settings due to its highly reactive nature. In the field of materials science, it may serve as a precursor or starting material for the production of specific polymers or materials with unique properties. Additionally, in industrial settings, monochloroacetylene can find application in certain chemical processes, although it requires strict safety measures due to its potential for explosive decomposition. Its primary role is as a reactive intermediate in chemical reactions and polymer synthesis, making it a specialized tool in chemistry and materials research but requiring careful handling and safety precautions in its usage due to its reactivity and hazardous nature.

Technology Process of MONOCHLOROACETYLENE

There total 65 articles about MONOCHLOROACETYLENE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 59.2%

3-(2,2-dimethylcyclopropyl)-3-chlorodiazirine (151538-87-3) → chloroacetylene (593-63-5) + 1-Chloro-3,3-dimethyl-cyclobutene + 1-Chloro-4,4-dimethyl-cyclobutene + isobutene (115-11-7,15220-85-6)

Guidance literature:

In chloroform-d1; at 21 ℃; for 0.5h; Product distribution; Mechanism; Rate constant; Irradiation; also in pentane, sealed tube, 60 and 80 deg C;

DOI:10.1021/j100152a056

Reference yield:

2-iodovinyl chloride (20244-71-7) + water (7732-18-5) → chloroacetylene (593-63-5) + hydrogen iodide (10034-85-2)

Guidance literature:

at 150 ℃;

Reference yield:

1,2-Dichloroethylene (540-59-0,43695-79-0) → chloroacetylene (593-63-5)

Guidance literature:

With potassium;

upstream raw materials:

1,2-Dichloroethylene

1,1,1,2-tetrachoroethane

Trichloroethylene

cis-1,2-Dichloroethylene

Downstream raw materials:

(Z)-1,2-dichloro-1-p-tolylsulfanyl-ethene

cis-1-chloro-2-(4-chloro-phenylsulfanyl)-ethylene

indole

cis-1-chloro-2-p-tolylsulfanyl-ethene

Refernces

• 1、 Umemoto, Masayuki,Seki, Kanekazu,Shinohara, Hisanori,Nagashima, Umpei,Nishi, Nobuyuki,et al.. "Photofragmentation of mono- and dichloroethylenes: Translational energy measurements of recoiling Cl and HCl fragments". . p. 1657 - 1666. Retrieved 1985.
• 2、 McManus et al.. "". . p. 4272. Retrieved 1968.
• 3、 Lee, Yu-Jinn,Lee, Ya-Rong,Chou, Chih-Chiang,Lin, Shen-Maw. "The C-Cl bond fissions from the photolysis of CHClCCl2 at 193 nm". . p. 346 - 347. Retrieved 1998.
• 4、 He, Guo-xin,Yang, Yung-an,Huang, Yibo,Gordon, Robert J.. "Distribution of Rotational States in Half-Collisions: 193-nm Photolysis of Dichloroethylene". . p. 2186 - 2193. Retrieved 1993.
• 5、 Hofmann,K.A.,Kirmreuther. "-". . p. 4233. Retrieved 1909.
• 6、 Levy, Ophir,Bino, Avi. "Metal ions do not play a direct role in the formation of carbon-carbon triple bonds during reduction of trihaloalkyls by CrII or V II". supporting information. p. 15944 - 15947. Retrieved 2013/02/23.