Benzaldehyde, O-acetyloxime

Base Information

• Chemical Name: Benzaldehyde, O-acetyloxime
• CAS No.: 19433-13-7
• Molecular Formula: C9H9NO2
• Molecular Weight: 163.176
• Mol file: 19433-13-7.mol

Synonyms:

Chemical Property of Benzaldehyde, O-acetyloxime

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Benzaldehyde, O-acetyloxime

There total 15 articles about Benzaldehyde, O-acetyloxime which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 77.0%

vinyl acetate (108-05-4,9003-20-7) + Benzaldoxime (932-90-1) → O-Acetylbenzaldoxim (19433-13-7)

Guidance literature:

In di-isopropyl ether; at 30 ℃; for 6h; lipase from Pseudomonas cepacia;

DOI:10.1055/s-1993-25798

Reference yield:

benzophenone (119-61-9) + (E)-benzaldehyde O-acetyl oxime (80055-49-8) → methane (34557-54-5,27936-85-2) + ethane (74-84-0) + benzylidenamine (16118-22-2) + (Z)-N-methyl-1-phenylmethanimine (29086-12-2) + (Z)-benzaldoxime O-acetate (19433-13-7,80055-49-8) + benzonitrile (100-47-0) + benzaldehyde benzylidenehydrazone (28867-76-7) + N-benzylidenemethylamine (25521-74-8)

Guidance literature:

In benzene-d6; Photolysis;

DOI:10.1021/ma301959n

Reference yield:

syn-benzaldehyde oxime (932-90-1,622-31-1,140461-24-1,140461-25-2,622-32-2) → (Z)-benzaldoxime O-acetate (19433-13-7,80055-49-8)

Guidance literature:

Multi-step reaction with 2 steps

2: bei der Einw_. von Brom, Jod, Halogenwasserstoffen, konz. Mineralsaeuren oder Acetylchlorid

upstream raw materials:

acetic anhydride

Benzaldoxime

benzaldehyde

acetyl chloride

Downstream raw materials:

benzonitrile

benzenecarbothioamide

2-phenylbenzo[d]oxazole

(Z)-benzaldehyde oxime

Refernces

• 1、 Gao, Sen,Gao, Liming,Meng, Hong,Luo, Meiming,Zeng, Xiaoming. "Iron-catalyzed synthesis of benzoxazoles by oxidative coupling/cyclization of phenol derivatives with benzoyl aldehyde oximes". supporting information. p. 9886 - 9889. Retrieved 2017/09/11.
• 2、 Hoffman, Robert V.,Buntain, Gregory A.. "A New Synthesis of Oxime Derivatives from Carbonyl Compounds and N,O-Bis(trimethylsilyl)hydroxylamine". . p. 831 - 833. Retrieved 2007/10/02.