1264258-84-5

Basic information

• Product Name: dibromo(2,4-bis(2,6-diisopropylphenylimido)pent-3-yl)iron(III)
• CAS NO: 1264258-84-5
• Molecular Weight: 633.313
• Mol File: 1264258-84-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: dibromo(2,4-bis(2,6-diisopropylphenylimido)pent-3-yl)iron(III)(CAS DataBase Reference)
• NIST Chemistry Reference: dibromo(2,4-bis(2,6-diisopropylphenylimido)pent-3-yl)iron(III)(1264258-84-5)
• EPA Substance Registry System: dibromo(2,4-bis(2,6-diisopropylphenylimido)pent-3-yl)iron(III)(1264258-84-5)

Safety Data

• Hazardous Substances Data: 1264258-84-5(Hazardous Substances Data)

Upstream product

• 10031-26-2 iron (III) bromide 

Downstream Products

• 1264258-80-1 [FeBr(NO)(CH(C(Me)N(2,6-diisopropylphenyl))2)] 

Relevant articles and documents

Chemistry of nitrosyliron complexes supported by a β-diketiminate ligand

Several nitrosyl complexes of Fe and Co have been prepared using the sterically hindered Ar-nacnac ligand (Ar-nacnac = anion of [(2,6- diisopropylphenyl)NC(Me)]2CH). The dinitrosyliron complexes [Fe(NO)2(Ar-nacnac)] (1) and (Bu4N)[Fe(NO) 2(Ar-nacnac)] (2) react with [FeIII(TPP)Cl] (TPP = tetraphenylporphine dianion) to generate [FeII(NO)(TPP)] and the corresponding mononitrosyliron complexes. The factors governing NO transfer with dinitrosyliron complexes (DNICs) 1 and 2 are evaluated, together with the chemistry of the related mononitrosyliron complex, [Fe(NO)Br(Ar-nacnac)] (4). The synthesis and properties of the related cobalt dinitrosyl [Co(NO) 2(Ar-nacnac)] (3) is also discussed for comparison to DNICs 1 and 2. The solid-state structures of several of these compounds as determined by X-ray crystallography are reported.