3416-49-7

Basic information

• Product Name: Benzenamine, N-butyl-N-methyl-
• CAS NO: 3416-49-7
• Molecular Formula: C11H17N
• Molecular Weight: 163.263
• Mol File: 3416-49-7.mol
• Article Data: 20

Chemical Properties

• CAS DataBase Reference: Benzenamine, N-butyl-N-methyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzenamine, N-butyl-N-methyl-(3416-49-7)
• EPA Substance Registry System: Benzenamine, N-butyl-N-methyl-(3416-49-7)

Safety Data

• Hazardous Substances Data: 3416-49-7(Hazardous Substances Data)

Upstream product

• 50-00-0 formaldehyd 
• 1126-78-9 N-(n-butyl)aniline 
• 123-72-8 butyraldehyde 
• 100-61-8 N-methylaniline 
• 542-69-8 1-iodo-butane 
• 109-69-3 n-Butyl chloride 
• 110-68-9 N-n-butyl-N-methylamine 
• 108-86-1 bromobenzene 
• 24388-23-6 2-phenyl-4,4,5,5-tetramethyl-1,3,2-dioxoborole 
• 60-01-5 tributyrin 
• 591-50-4 iodobenzene 
• 124-38-9 carbon dioxide 
• 614-30-2 N-methyl-N-phenyl-benzenemethanamine 
• 103-84-4 Acetanilid 

Downstream Products

• 1126-78-9 N-(n-butyl)aniline 
• 366-29-0 N,N,N',N'-tetramethylbenzidine 
• 7137-77-1 N,N-dimethyl-4-{[methyl(phenyl)amino]methyl}aniline 
• 25413-69-8 N-butyl-N-nitroso-aniline 
• 614-00-6 N-methyl-N-nitrosoaniline 
• 56269-49-9 N-butyl-N-methyl-4-nitrobenzenamine 
• 156808-76-3 4-bromo-N-butyl-N-methylaniline 
• 943-41-9 N-methyl-N-nitroso-4-nitroaniline 
• 479-45-8 tetryl 
• 13475-69-9 N-butyl-N-methyl-2-nitrobenzenamine 
• 1236057-19-4 4-[(1H-indol-3-yl)methyl]-N-butyl-N-methylbenzenamine 
• 1236057-15-0 N-butyl-N-[(1-phenyl-1H-indol-3-yl)methyl]benzenamine 
• 6289-67-4 N-butyl-N-phenylbutyramide 
• 6590-43-8 N-butyl-N-phenylbenzenamine 

Relevant articles and documents

Visible-Light-Induced C(sp2)-C(sp3) Cross-Dehydrogenative-Coupling Reaction of N-Heterocycles with N-Alkyl- N-methylanilines under Mild Conditions

Disclosed herein is a cross-dehydrogenative-coupling reaction of N-heterocycles including 1,2,4-triazine-3,5(2H, 4H)-diones and quinoxaline-2(1H)-ones with N-methylanilines to form C(sp2)-C(sp3) under visible-light illumination and ambient air at room temperature. In this process, easily available Ru(bpy)3Cl2·6H2O serves as the catalyst, and air acts as the green oxidant. This method features high atom economy, environmental friendliness, and convenient operation and provides an efficient and practical access to aminomethyl-substituted N-heterocycles with extensive functional group compatibility in 40-86% yields.

Dirhodium-Catalyzed Chemo-and Site-Selective C-H Amidation of N, N-Dialkylanilines

A method for dirhodium-catalyzed C(sp 3)-H amidation of N, N-dimethylanilines was developed. Chemoselective C(sp 3)-H amidation of N-methyl group proceeded exclusively in the presence of C(sp 2)-H bonds of the electron-rich aromatic ring. Site-selective C(sp 3)-H amidation proceeded exclusively at the N-methyl group of N-methyl-N-Alkylaniline derivatives with secondary, tertiary, and benzylic C(sp 3)-H bonds α to a nitrogen atom.

Mn-Catalyzed Selective Double and Mono-N-Formylation and N-Methylation of Amines by using CO2

Functionalization of amines by using CO2 is of fundamental importance considering the abundance of amines and CO2. In this context, the catalytic formylation and methylation of amines represent convenient and successful protocols for selective CO2 utilization as a C1 building block. This study represents the first example of selective catalytic double N-formylation of aryl amines by using a dinuclear Mn complex in the presence of phenylsilane. This robust system also allows for selective formylation and methylation of amines under a range of conditions.